Synthesis and structure of neutral and cationic pentahaloarylpalladium(II) isonitrile complexes |
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| Authors: | R Usn J Fornis P Espinet E Lalinde |
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| Institution: | Department of Inorganic Chemistry, University of Zaragoza, Zaragoza Spain |
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| Abstract: | Complexes of the types (a) trans- and cis-Pd(C6X5)2 (CNR)2], (b) trans- Pd(C6X5)Cl(CNR)2] and (c) Pd(C6X5)(CNR)3]ClO4 (X = F or Cl;R = But cyclohexyl or p-tolyl) have been made by replacement of the tetrahydrothiophen or Cl groups of appropriate precursors by isonitrile. Their structures have been assigned on the basis of their IR and 1H NMR spectra. |
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