| 六(乙氧基吡咯烷酮)三聚磷腈的合成与表征 |
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| 引用本文： | 殷跃凡,黄荣,李艳梅,毕韵梅.六(乙氧基吡咯烷酮)三聚磷腈的合成与表征[J].化学通报,2007,70(7):552-554. |
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| 作者姓名： | 殷跃凡 黄荣 李艳梅 毕韵梅 |
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| 作者单位： | 云南师范大学化学化工学院 昆明650092(殷跃凡，李艳梅，毕韵梅)，云南大学化学科学与工程学院 昆明650031(黄荣) |
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| 基金项目： | 国家自然科学基金(20364002)，中国科学院“西部之光”人才培养计划资助项目 |
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| 摘 要： | 以N-羟乙基吡咯烷酮与氢化钠作用生成相应的钠盐,再将此钠盐与六氯三聚磷腈(HCCP)发生亲核取代反应,合成了六(乙氧基吡咯烷酮)三聚磷腈,用IR、31P NMR、1H NMR、13C NMR、DEPT、FABMS等现代谱学技术对其结构进行了表征。生物活性试验表明,此化合物1mg/mL时对腐生线虫Panagrellus redivivus的72h致死率为52·7%。
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| 关 键 词： | 六(乙氧基吡咯烷酮)三聚磷腈 N-羟乙基吡咯烷酮 合成 |
| 修稿时间： | 2006-07-28 |
Synthesis and Characterization of Hexakis [2- ( 2- oxo- 1 - pyrrolidinyl) Cyclotriphosphazene] |
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| Yin Yuefan,Huang Rong,Li Yanmei,Bi Yunmei.Synthesis and Characterization of Hexakis [2- ( 2- oxo- 1 - pyrrolidinyl) Cyclotriphosphazene][J].Chemistry,2007,70(7):552-554. |
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| Authors: | Yin Yuefan Huang Rong Li Yanmei Bi Yunmei |
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| Institution: | 1.College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092; 2 .College of Chemistry Science and Engineering, Yunnan University, Kunming 650031 |
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| Abstract: | Synthesis,characterization and biological activity of hexakis 2-(2-oxo-1-pyrrolidinyl) cyclotri-phosphazene] were described in this paper.The title compound was prepared by nucleophilic substitution reaction of hexa-chlorocyclotriphosphazene with sodium 1-(2-hydroxyethyl)-2-pyrrolidone which was obtained by the reaction of 1-(2-hydro-xyethyl)-2-pyrrolidone with sodium hydride.The results showed that the compound was able to kill 52.7% of the Panagrellus redivivus at 1mg/mL within 72 hours. |
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| Keywords: | Hexakis[2-(2-oxo-1-pyrrolidinyl)cyclotriphosphazene] 1-(2-Hydroxyethyl)-2-pyrrolidone Synthesis |
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