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Tb-MOFs在荧光检测方面的研究进展
引用本文:赵小杨,李红喜,杨启山.Tb-MOFs在荧光检测方面的研究进展[J].化学通报,2020,83(12):1089-1097,1103.
作者姓名:赵小杨  李红喜  杨启山
作者单位:内蒙古科技大学 化学与化工学院 包头 014010;内蒙古科技大学 化学与化工学院 包头 014010;内蒙古科技大学 化学与化工学院 包头 014010
基金项目:内蒙古自然科学基金项目(2016ZD05)资
摘    要:镧系离子特殊的电子排布使镧系有机骨架材料(Ln-MOFs)具有独特的发光性质,通过骨架和不同客体分子间的相互作用,可实现对诸多物质的荧光检测。其中,以铽离子(Tb3+)为中心构筑的Tb-MOFs具有更优良的光学性能和更高的检测灵敏度,是一种极具潜力的高效荧光探针。本文以稀土Tb3+为主线,综述了近年来国内外Tb-MOFs材料在阴阳离子、有机小分子、生物分子荧光检测方面的研究进展,并对未来发展趋势进行了展望。

关 键 词:镧系-有机骨架材料  发光  荧光检测  检测机理
收稿时间:2020/4/21 0:00:00
修稿时间:2020/5/14 0:00:00

Research Progress in Tb-MOFs for Fluorescence Detection
Zhao Xiaoyang,Li Hongxi,Yang Qishan.Research Progress in Tb-MOFs for Fluorescence Detection[J].Chemistry,2020,83(12):1089-1097,1103.
Authors:Zhao Xiaoyang  Li Hongxi  Yang Qishan
Institution:School of Chemistry and Chemical Engineering,Inner Mongolia University of Science and Technology,Baotou,014010,School of Chemistry and Chemical Engineering,Inner Mongolia University of Science and Technology,Baotou,014010,School of Chemistry and Chemical Engineering,Inner Mongolia University of Science and Technology,Baotou,014010
Abstract:anthanide organic frameworkmaterials (Ln-MOFs) have unique luminescence properties due to the special electron configuration of lanthanide ions.Fluorescence detection of many substances can be realized through the interaction between the framework and different guest molecules. Among them, Tb-MOFs constructed with terbium ion (Tb3+) as the center have better optical performance and higher detection sensitivity, and they are potential high-efficiency fluorescent probes. In this paper, rare earth Tb3+as the main line,the research progress of Tb-MOFs materials in the fluorescencedetection of anion and cation, organic small molecule and biological molecule was reviewed, and the future development trend was prospected.
Keywords:Lanthanide - organic frame material  Luminescence  Fluorescence detection  Detection mechanism
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