| 61-甲基-61-[12-(N,N-四氯邻苯二甲酰基)脱氢枞胺]-1,2-亚甲基富勒烯[60]的合成 |
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| 引用本文： | 周 志,林中祥.61-甲基-61-[12-(N,N-四氯邻苯二甲酰基)脱氢枞胺]-1,2-亚甲基富勒烯[60]的合成[J].化学通报,2015,78(1):80-84. |
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| 作者姓名： | 周 志 林中祥 |
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| 作者单位： | 凯里学院化学与材料工程学院 凯里,南京林业大学化学工程学院 南京 |
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| 基金项目： | 国家自然科学基金项目（面上项目，重点项目，重大项目） |
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| 摘 要： | 以脱氢枞胺为原料,经氨基酰化、12位乙酰化、与对甲苯磺酰肼形成对甲苯磺酰腙衍生物,再通过卡宾中间体与C60进行2+1]环加成反应合成了C60-脱氢枞胺衍生物。目标化合物经IR,UV-Vis,1H NMR,13C NMR,MALDI-TOF MS表征,所得化合物为6,6]闭环结构C60加成产物。
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| 关 键 词： | 脱氢枞胺 富勒烯 环加成 合成方法 |
| 收稿时间： | 4/7/2014 12:00:00 AM |
| 修稿时间： | 6/8/2014 12:00:00 AM |
Synthesis of 61-Methyl-61-[12-(N,N-tetrachlorophthaloyl)dehydroabietylamine] -1,2-methanofullerene[60] |
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| Zhou Zhi and Lin Zhongxiang.Synthesis of 61-Methyl-61-[12-(N,N-tetrachlorophthaloyl)dehydroabietylamine] -1,2-methanofullerene[60][J].Chemistry,2015,78(1):80-84. |
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| Authors: | Zhou Zhi and Lin Zhongxiang |
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| Institution: | College of Chemistry and Materials Engineering,Kaili University,College of Chemical Engineering,Nanjing Forestry University |
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| Abstract: | The C60-dehydroabietylamine derivative was synthesized from dehydroabietylamine via amidation, 12-acetylation and the reaction with p-tosylhydrazide yielded the corresponding p-tosylhydrazone, then through 2 1]-cycloaddition of the carbene intermediate with C60. The structure was characterized by IR, UV-vis, 1H NMR, 13C NMR, MALDI-TOF MS, the results showed that the target compound is 6, 6]-closed C60 adduct. |
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| Keywords: | dehydroabietylamine fullerenes cycloaddition synthesis methods |
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