| 三级胺及酰胺硝解研究进展 |
| |
| 引用本文： | 欧育湘,刘进全,王才,吕连营.三级胺及酰胺硝解研究进展[J].化学通报,2004,67(8):560-565,559. |
| |
| 作者姓名： | 欧育湘 刘进全 王才 吕连营 |
| |
| 作者单位： | 北京理工大学材料学与工程学院,北京,100081;中国科学院化学研究所,北京,100080 |
| |
| 基金项目： | 国防科工委预研基金资助项目 (12 0 6 0 4 5 186 7) |
| |
| 摘 要： | 综述了三级叔胺及酰胺硝解的近期研究进展，重点是已作为或有可能成为高能量密度化合物硝胺的合成。讨论了三级胺及酰胺的硝解历程，汇集了常用的硝化及硝解系统。详细阐述了烷基叔胺、叔酰胺、烷基酰基叔胺。特别是多环笼形叔胺和叔酰胺的硝解反应及硝解条件。
|
| 关 键 词： | 含能材料 硝胺 硝解 |
Recent Development of Nitrolysis of Tertiary Amines and Amides |
| |
| Abstract: | This paper reviews the recent development of nitrolysis of tertiary amines and amides, focusing on the synthesis of nitramines which have been used or have great potential for the application as high energy density compounds.The nitrolysis mechanisms of tertiary amines and amides are proposed and the widely used nitrating agents for nitrolysis are summarized.The achievements acquired mainly during the last decade on the nitrolysis of alkyl tertiary amines,tertiary amides, alkyl-acetyl tertiary amines,and especially polycyclic caged tertiary amines and amide are discussed in detail. |
| |
| Keywords: | Energetic material Nitramine Nitrolysis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
