| 尿素羰基化作用研究进展 |
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| 引用本文： | 王娜,赵新强,安华良,王延吉.尿素羰基化作用研究进展[J].化学通报,2011,74(6):491-496. |
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| 作者姓名： | 王娜 赵新强 安华良 王延吉 |
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| 作者单位： | 绿色化工与高效节能河北省重点实验室河北工业大学化工学院; |
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| 基金项目： | 国家自然科学基金项目(20976035)资助 |
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| 摘 要： | 综述了尿素作为羰基化试剂合成氨基酸酯或碳酸酯类化合物及脲类化合物的研究进展,详细讨论了合成反应中所涉及的催化剂、反应机理和工艺条件,指出通过尿素醇解或胺解反应合成相应化合物是一条绿色工艺路线,具有广阔应用前景.
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| 关 键 词： | 尿素 羰基化 醇解 胺解 |
Research Progress on Urea as a Carbonylation Reagent |
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| Wang Na,Zhao Xinqiang,An Hualiang,Wang Yanji.Research Progress on Urea as a Carbonylation Reagent[J].Chemistry,2011,74(6):491-496. |
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| Authors: | Wang Na Zhao Xinqiang An Hualiang Wang Yanji |
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| Institution: | Wang Na,Zhao Xinqiang,An Hualiang,Wang Yanji(Hebei Provincial Key Lab of Green Chemical Technology & High Efficient Energy Saving,School of Chemical Engineering & Technology,Hebei University of Technology,Tianjin 300130) |
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| Abstract: | The research progress on syntheses of carbamates or carbonates and urea derivatives by using urea as a carbonylation reagent involving catalyst,reaction mechanism and process conditions was reviewed.These processes show more advantages than the traditional routes,especially in the respect of safety and environmental friendliness,and hence have wide application prospect. |
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| Keywords: | Urea Carbonylation Alcoholysis Aminolysis |
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