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智能表面
引用本文:孙亚斌,丁小斌,郑朝晖,成煦,彭宇行.智能表面[J].化学通报,2006,69(4):252-260.
作者姓名:孙亚斌  丁小斌  郑朝晖  成煦  彭宇行
作者单位:中国科学院成都有机化学研究所 成都610041中国科学院研究生院北京100039(孙亚斌),中国科学院成都有机化学研究所 成都610041(丁小斌,郑朝晖,成煦,彭宇行)
摘    要:智能表面就是在基材表面自组装成单分子层或接枝(环境敏感性)线性高分子刷,通过环境刺激,使表面性能如亲水/憎水、酸性/碱性、导电/绝缘、粘结/排斥、吸附/脱附等发生(可逆)变化。根据环境刺激的类型可以分为以下几类:溶剂响应、温敏性、电场响应、pH响应型以及光敏性智能表面。本文对此五种类型的智能表面作一介绍。

关 键 词:智能材料  智能表面  高分子刷  单分子层
收稿时间:2005-08-20
修稿时间:2005-08-202005-10-17

Smart Surface
Sun Yabin,Ding Xiaobin,Zheng Zhaohui,Cheng Xu,Peng Yuxing.Smart Surface[J].Chemistry,2006,69(4):252-260.
Authors:Sun Yabin  Ding Xiaobin  Zheng Zhaohui  Cheng Xu  Peng Yuxing
Institution:1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 ; 2.Graduate School of Chinese Academy of Sciences, Beijing 100039
Abstract:In this paper, the current state of affairs within the research field of adaptive and environmentally sensitive surfaces designed to respond to external stimuli in a controlled and predictable manner is introduced. These smart surfaces can switch their interfacial properties reversibly, such as hydrophobic or hydrophilic, acidic or basic, conductive or non-conductive, adhesive or repellent, being able to release or adsorb some species. According to environmental stimulations, they can be divided into five groups which are solvent_adaptive surface, thermo_responsive surface, pH-sensitive surface, electrical potential responsive surface and photo_responsive surface. Smart surfaces with these patterns are also introduced here.
Keywords:Smart surface  Polymer brush  Self-assemble monolayer  Intelligent materials  Adaptive materials  
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