| 胺功能化配体多孔配位聚合物材料的碳捕捉和封存研究进展 |
| |
| 引用本文： | 刘双,刘澜涛.胺功能化配体多孔配位聚合物材料的碳捕捉和封存研究进展[J].化学通报,2019,82(2):108-113. |
| |
| 作者姓名： | 刘双 刘澜涛 |
| |
| 作者单位： | 商丘师范学院化学化工学院 商丘476000;商丘师范学院化学化工学院 商丘476000 |
| |
| 基金项目： | 国家自然科学基金项目（21503129、21572126、21675109）, 河南省高等学校重点科研项目（15A150073） |
| |
| 摘 要： | 近十年,多孔配位聚合物(porous coordination polymers, PCPs)因其晶体结构中可调节的孔道尺寸、形状以及化学功能化,在小分子的选择性吸附及分离领域受到了极大的关注。基于环境问题的严峻性,胺功能化PCPs材料对煤电厂燃烧废气中CO2优异的选择性吸附性能,使其在该领域拥有较好的应用潜力。本文综述了含末端氨基配体的PCPs材料应用于二氧化碳捕捉及存储的代表性工作,并对所存在的问题及发展方向进行了分析总结。
|
| 关 键 词： | 配位聚合物 胺功能化 二氧化碳 多孔材料 |
| 收稿时间： | 2018/8/15 0:00:00 |
| 修稿时间： | 2018/9/30 0:00:00 |
Recent Advances in Carbon Capture and Sequestration of PCPs Synthesized by Amine-Functionalization Ligands |
| |
| Liu Shuang and Liu Lantao.Recent Advances in Carbon Capture and Sequestration of PCPs Synthesized by Amine-Functionalization Ligands[J].Chemistry,2019,82(2):108-113. |
| |
| Authors: | Liu Shuang and Liu Lantao |
| |
| Institution: | Shangqiu Normal University,Shangqiu Normal University |
| |
| Abstract: | Over the decade, porous coordination polymers (PCPs) have attracted significant attention in the area of selective adsorption & separation of small molecules due to their unique crystal structure with the tunable pore size, pore shape and chemical functionalization. Based on the severity of environmental problems, amines modified PCPs have exhibited outstanding selective adsorption property for carbon dioxide from flue gas, which offer great potential application in this field. In this review, the problems and development of PCPs synthesized by bridging ligands contain terminal amines groups are discussed alongside marked examples applied for carbon dioxide capture and sequestration. |
| |
| Keywords: | coordination polymer amine-functionalization carbon dioxide porous materials |
| 本文献已被 万方数据 等数据库收录！ |
| 点击此处可从《化学通报》浏览原始摘要信息 |
| 点击此处可从《化学通报》下载免费的PDF全文 |
