氨基功能化金属有机骨架光催化剂的制备及性能研究

氨基功能化金属有机骨架材料(Metal-organic frameworks,MOFs)是一种非常具有吸引力的功能化MOFs,其兼具MOFs的高比表面积、孔道易调控及氨基的可后处理修饰的性能。通过简单的化学反应可实现功能基团的转化,从而制得新型的功能化MOFs,在气体存储、药物载体、选择性吸附气体小分子和催化等领域具有潜在的应用价值,因此开发氨基功能化的MOFs备受人们关注。本文综述了近年来氨基功能化MOFs在催化和吸附领域的研究进展,包括氨基功能化MOFs的制备方法、影响因素以及在环境方面的应用,并对今后的发展前景进行了展望。

Preparation and Properties of Amino Functionalized Metal Organic Framework Photocatalysts

Compared with traditional MOFs, the amino functionalized metal-organic frameworks are very attractive materials. They have some special physical and chemical properties and also have the advantages of MOFs and amino functional groups, such as specific surface area, pore easy regulation and amino modification can postproce performance for MOFs. Through the simple chemical reaction can realize the conversion of functional groups, so as to prepare novel functionalized MOFs in gas storage, drug carrier, have the potential application value of selective adsorption of small molecules and the development of photocatalysis. Thus the amino functionalized MOFs have attracted much attention. This paper summarizes the research progress of amino functionalized MOFs in catalysis and adsorption field in recent years, including the preparation methods, influencing factors, environmental applications of amino functionalized MOFs. Finally, the prospect of the development is prospected.