N-杂环卡宾配体在聚合反应中的研究进展

N-杂环卡宾配体的优异催化性能引起了人们的广泛关注, 已成功应用于多种烯烃聚合反应。本文结合N-杂环卡宾的相关研究报道,首先简要介绍N-杂环卡宾,随后重点介绍N-杂环卡宾在开环易位聚合、烯烃配位聚合和原子转移自由基聚合等聚合反应的应用。在此基础上,指出了今后N-杂环卡宾配体在聚合反应研究的发展方向。

Research Advances of N-Heterocyclic Carbene Ligands in Polymerization

N-heterocyclic carbene ligands have attracted extensive attention, due to their excellent catalytic performance. N-heterocyclic carbene ligands have been widely utilized in a variety of olefin polymerization reactions. According to the recent reports, N-heterocyclic carbene were briefly introduced, firstly. The recent research advances of the application in ring-opening metathesis polymerization, olefin coordination polymerization, atom transfer radicalSpolymerization, and other polymerization were focused on. The development trends of N-heterocyclic carbene ligands in polymerization were proposed, on the basis.