| 低共熔溶剂催化有机合成反应的研究进展 |
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| 引用本文： | 丁阳,刘梦格,卜健行,肖雄坤,王炜,盛文兵.低共熔溶剂催化有机合成反应的研究进展[J].化学通报,2022,85(9):1070-1076，1061. |
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| 作者姓名： | 丁阳 刘梦格 卜健行 肖雄坤 王炜 盛文兵 |
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| 作者单位： | 湖南中医药大学,湖南中医药大学药学院,湖南中医药大学药学院,湖南中医药大学药学院,湖南中医药大学药学院,湖南中医药大学药学院 |
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| 基金项目： | 湖南省自然科学基金项目(2021JJ30502)、长沙市自然科学基金项目(kq2014092)和2020年度国家级大学生创新创业训练计划项目(S202010541042)资助 |
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| 摘 要： | 低共熔溶剂(DESs)是一种新型的离子液体(ILs)类似物,与传统有机溶剂、离子液体相比,DESs具有低毒、廉价、易于合成、生物可降解性等特点,因此在众多领域广受关注。近年来DESs在有机合成领域备受关注,被广泛用作合成反应的溶剂、催化剂、反应物等,在有机反应方面存在很大发展空间,本文综述了DESs在有机合成反应中的应用,重点讨论其在氧化还原反应、取代反应、缩合反应、环化反应等方面的研究进展,为其开发应用提供新思路。
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| 关 键 词： | 低共熔溶剂 有机合成 HBD HBA |
| 收稿时间： | 2022/1/26 0:00:00 |
| 修稿时间： | 2022/3/5 0:00:00 |
Progress of Organic Synthesis Catalyzed by Deep Eutectic Solvents |
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| Ding Yang,Liu Mengge,Bu Jianxing,Xiao Xingkun,Wang Wei and Sheng Wenbing.Progress of Organic Synthesis Catalyzed by Deep Eutectic Solvents[J].Chemistry,2022,85(9):1070-1076，1061. |
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| Authors: | Ding Yang Liu Mengge Bu Jianxing Xiao Xingkun Wang Wei and Sheng Wenbing |
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| Abstract: | Deep eutectic solvents (DESs) is a new type of ionic liquids (ILs) analogs, compared with traditional organic solvents and ionic liquid, DESs has the characteristics about low toxicity, cheap, easy synthesis, biodegradability, so it is got wide attention in many fields. In recent years, DESs has attracted much attention in the field of organic synthesis, and widely used as solvents, catalysts and reactants in synthesis reactions. There is a great development space for the specific organic reactions. This paper reviews the application of DESs in organic synthesis reactions, focusing on their research progress in redox reaction, substitution reaction, condensation reaction, cyclic reaction, which will provide new ideas for their application and development. |
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| Keywords: | Deep eutectic solvents (DESs) Organic synthesis Hydrogen bond donor Hydrogen bond acceptor |
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