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硼烯:从理论模型到探究应用
引用本文:曹福臣,贺天平.硼烯:从理论模型到探究应用[J].化学通报,2022,85(7):884-890.
作者姓名:曹福臣  贺天平
作者单位:山西大学科学技术史研究所 太原 030006,山西大学科学技术史研究所 太原 030006
摘    要:1995年,德国科学家布斯塔尼通过理论计算提出了硼团簇的构造法则——“Aufbau原则”,为硼烯的理论模型研究奠定了基础。在新的理论和计算方法不断提出的背景下,硼烯的理论模型得到了进一步的完善,2014年,美国布朗大学的王来生正式提出“硼烯”这一概念,至此二维硼烯的概念得到了广泛的确信。2015年,研究者首次报道在Ag(111)衬底上生成二维硼烯薄膜。随后,科学家们通过实验探究发现硼烯在超导材料、电池电极材料、催化剂、储氢等领域有巨大的应用前景。硼烯的发展史揭示了理论和实验交互验证的新型科学发展模式,促进了二维材料发展观的演进。

关 键 词:硼烯  理论模型  实验制备  应用前景
收稿时间:2021/11/2 0:00:00
修稿时间:2021/11/25 0:00:00

Boronene: From Theoretical Model to Inquiry application
CAO Fu-chen and HE Tian-ping.Boronene: From Theoretical Model to Inquiry application[J].Chemistry,2022,85(7):884-890.
Authors:CAO Fu-chen and HE Tian-ping
Institution:Institute for the History of Science and Technology,Shanxi University,Taiyuan,030006,Institute for the History of Science and Technology,Shanxi University,Taiyuan,030006
Abstract:In 1993, Chinese scientist Aoqing Tang proposed a conjugated polyhedron based on carbon and boron through theoretical calculations, which laid the foundation for the theoretical model study of boronene. Subsequently, the theoretical model of boronene was further improved under the continuous proposals of new theories and calculation methods. In 2007, Tang Hui of Yale University in the United States and others put forward a theoretical model of boronene that is completely on the same plane through theoretical calculations. The concept of boronene has been widely believed. In 2015, Mannix of the United States and Wu Kehui of China respectively formed borene films on Ag(111) substrates at the same time. Subsequently, the scientists discovered through experimental exploration that boronene has huge application prospects in the fields of superconducting materials, battery electrode materials, catalysts, and hydrogen storage. The development history of boronene reveals a new scientific development model of interactive verification of theory and experiment, and promotes the evolution of the development concept of two-dimensional materials.
Keywords:Boronene  Theoretical  Model  Experimental  Preparation  Application  Prospects
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