| C_(60)与N-羧甲基脱氢枞胺的1,3-偶极环加成反应研究 |
| |
| 引用本文： | 熊垚,林中祥,范旭,邓慧敏.C_(60)与N-羧甲基脱氢枞胺的1,3-偶极环加成反应研究[J].化学通报,2009,72(5). |
| |
| 作者姓名： | 熊垚 林中祥 范旭 邓慧敏 |
| |
| 作者单位： | 熊垚,林中祥,范旭,Xiong Yao,Lin Zhongxiang,Fan Xu(南京林业大学化学工程学院,南京,210037);邓慧敏,Deng Huimin(中山大学分析测试中心,广州,510275)
|
| |
| 摘 要： | 以脱氢枞胺的衍生物N-羧甲基脱氰枞胺与C60及多聚甲醛为原料,于N2保护下在甲苯中回流48h,经1,3-偶极环加成反应,得到脱氢枞胺基团加成度不同的三种C60吡咯烷衍生物,并对它们的结构进行了表征.
|
| 关 键 词： | C60脱氢枞胺1 3-偶极环加成 吡咯烷衍生物 |
Study on 1,3-Dipolar Cycloaddition of C_(60) with N-Carboxymethyl Dehydroabietylamine |
| |
| Xiong Yao,Lin Zhongxiang,Fan Xu,Deng Huimin.Study on 1,3-Dipolar Cycloaddition of C_(60) with N-Carboxymethyl Dehydroabietylamine[J].Chemistry,2009,72(5). |
| |
| Authors: | Xiong Yao Lin Zhongxiang Fan Xu Deng Huimin |
| |
| Institution: | 1College of Chemical Engineering;Nanjing Forest University;Nanjing 210037;2Instrumental Analysis & Research Center;Sun Yat-sen University;Guangzhou 510275 |
| |
| Abstract: | Three C_60 pyrrolidine derivatives with different addition degrees of dehydroabietylamine groups were synthesized through the 1,3-dipolar cycloaddition of N-carboxymethyl dehydroabietylamine with C_60 and formaldehyde in toluene for refluxing 48 hours in the atmosphere of nitrogen,and their structures were characterized. |
| |
| Keywords: | C60 Dehydroabietylamine 1 3-Dipolar cycloaddition Pyrrolidine derivative |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
