| 醛亚胺的不对称Strecker反应研究进展 |
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| 引用本文： | 唐贝,李高伟.醛亚胺的不对称Strecker反应研究进展[J].化学研究,2013(1):104-110. |
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| 作者姓名： | 唐贝 李高伟 |
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| 作者单位： | 河南省医药学校;商丘师范学院化学系 |
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| 摘 要： | α-氨基腈不仅可以很容易地转化为α-氨基酸,而且是合成许多具有生物活性的天然产物和药物的重要中间体.醛亚胺的不对称Strecker反应作为制备光学活性α-氨基腈的直接而有效的方法之一,已被广泛接受.作者介绍了醛亚胺的不对称Strecker反应研究进展.
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| 关 键 词： | 不对称催化 醛亚胺 Strecker反应 综述 |
Developments in catalytic asymmetric Strecker reaction of aldimines |
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| TANG Bei,LI Gao-wei.Developments in catalytic asymmetric Strecker reaction of aldimines[J].Chemical Research,2013(1):104-110. |
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| Authors: | TANG Bei LI Gao-wei |
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| Institution: | 1.Henan Pharmaceutical School,Kaifeng 475001,Henan,China;2.Department of Chemistry, Shangqiu Normal University,Shangqiu 476000,Henan,China) |
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| Abstract: | a-Aminonitriles can be easily converted to a-amino acids, and is an important inter- mediate for the synthesis of many biologically active natural products and drugs. The asymmetric Strecker reaction of the aldimine as a direct and affective method of synthesis of op- tically active α-aminonitriles has been widely accepted. In this current paper, the developments in catalytic asymmetric Strecker reaction of aldimines is introduced. |
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| Keywords: | asymmetric catalysis aldimine Strecker reaction review |
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