| 电流密度对钙磷沉积层组成和结构的影响(英文) |
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| 引用本文： | 张建民,石秋芝,杨长春,许金木.电流密度对钙磷沉积层组成和结构的影响(英文)[J].化学研究,2002,13(2):5-7. |
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| 作者姓名： | 张建民 石秋芝 杨长春 许金木 |
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| 作者单位： | 郑州大学化学系,郑州,450052 |
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| 基金项目： | FoundationofZhengzhouUniversity |
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| 摘 要： | 用X射线衍射、激光拉曼光谱以及等离子体原子发射光谱等技术研究了电化学沉积钙磷陶瓷过程中 ,电流密度对电沉积层组成和结构的影响 .实验表明阴极表面得到的沉积物是几种钙磷盐组成的混合物 ,且其成份随电流密度的改变而发生较大的变化 .在电解液温度为 75℃条件下 ,当控制电流密度较低时 ,沉积层主要由CaHPO4· 2H2 O (DCPD)和Ca8H2 (PO4) 6· 5H2 O (OCP)组成 ;随着电流密度的增加 ,阴极表面逐渐生成Ca3 (PO4) 2 ·nH2 O (TCP)和Ca10 (PO4) 6(OH) 2 (HAP) .当电流密度大于 5mA/cm2 时 ,电沉积层的主要成份为羟基磷灰石 (HAP) .
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| 关 键 词： | 电沉积 生物陶瓷 磷酸钙 羟基磷灰石 |
Influence of Current Density on the Composition and Structure of Calcium Phosphate Coatings |
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| Abstract.Influence of Current Density on the Composition and Structure of Calcium Phosphate Coatings[J].Chemical Research,2002,13(2):5-7. |
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| Authors: | Abstract |
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| Abstract: | In the paper the effect of current density on the composition and structure of electrodeposition coatings of calcium phosphates was studied by XRD、Raman spectrum and ICP/AES techniques. The experimental results showed that different phases of calcium phosphates may be formed on the substrate depending on the cathodic current density, and hydroxyapatite (HAP) was the main constituent when the current density was equal to or more than 5 mA/cm2 at 75℃. |
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| Keywords: | electrodeposition bioceramic calcium phosphate hydroxyapatite |
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