| TX-100反相微乳液的缔合结构研究 |
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| 引用本文： | 曾红霞,张戈,王娟芳,吴晶,李之平,汪汉卿.TX-100反相微乳液的缔合结构研究[J].化学研究,1999,10(1):1. |
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| 作者姓名： | 曾红霞 张戈 王娟芳 吴晶 李之平 汪汉卿 |
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| 作者单位： | 1. 中国科学院新疆化学研究所,乌鲁木齐,830011
2. 中国科学院兰州化学物理研究所,兰州,730000 |
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| 摘 要： | 对ＴＸ－１００、正戊醇、正己醇、正庚醇、正辛醇及辛烷形成的反相微乳液用ＥＳＲ自旋标记方法进行了研究，结果认为反相微乳液的形成过程伴随着表面活性剂链排列的变化，在加入水量较少时栅状区域的表面活性剂链排列拥挤，进一步的水化作用使其排列疏松。而疏水性强的探针则表明水化作用渗透到了反相微乳液的疏水区域。
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| 关 键 词： | 电子顺磁共振 反相微乳液 表面活性剂 |
| 文章编号： | 1008-1011(1999)-01-0025-04 |
| 修稿时间： | 1999-01-11 |
ESR Study on the Associated Structure of TX-100 Reverse Microemulsion System |
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| Zeng Hongxia,Zhang Ge,Wang Juanfang,Wu Jing,Li Zhiping,Wang Hanqing.ESR Study on the Associated Structure of TX-100 Reverse Microemulsion System[J].Chemical Research,1999,10(1):1. |
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| Authors: | Zeng Hongxia Zhang Ge Wang Juanfang Wu Jing Li Zhiping Wang Hanqing |
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| Abstract: | The associated structure of TX-100 reverse microemulsion formed by octane and different cosurfactants such as petanol,hexanol,heptanol and octanol is studied.It's shown that surfactant chains packed closely as water addition are small,and it becomes loose with hydration process continue.Results labeled by hydrophilic probe show that hydration action permeates into hydrophilic region of reverse microemulsion. |
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| Keywords: | ESR reverse microemulsion spin-label |
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