| 分子氧/醛/过渡金属盐体系选择性氧化二苯硫醚的研究(英文) |
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| 引用本文： | 宋国强,王钒,吕晓玲.分子氧/醛/过渡金属盐体系选择性氧化二苯硫醚的研究(英文)[J].化学研究,2000,11(1):41-42,47. |
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| 作者姓名： | 宋国强 王钒 吕晓玲 |
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| 作者单位： | 江苏石油化工学院精细化工重点学科江苏常州213016 |
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| 基金项目： | 江苏省青年科技人才基金，BQ96018， |
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| 摘 要： | 在温和的反应条件和三氧化二铁或三氧化二钴存在下 ,结合使用分子氧和正戊醛以及采用“一步法”的方式 ,可有效和选择性地发生二苯硫醚氧化成相应的亚砜或砜的反应。与传统的氧化剂相比 ,此方法更安全和简便。
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| 关 键 词： | 二苯硫醚 过渡金属盐 分子氧 醛 选择性氧化 |
| 文章编号： | 1008-1011(2000)01-0041-03 |
Selective Oxidation of Phenyl Sulfide Catalyzed by Transition Metal Salts with Molecular Oxygen and Aldehyde |
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| Song Guoqiang,Wang Fan,Lu Xiaoling.Selective Oxidation of Phenyl Sulfide Catalyzed by Transition Metal Salts with Molecular Oxygen and Aldehyde[J].Chemical Research,2000,11(1):41-42,47. |
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| Authors: | Song Guoqiang Wang Fan Lu Xiaoling |
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| Abstract: | Efficient and selective oxidation of phenyl sulfide to the corresponding sulfoxide or sulfone was achieved in moderate to high yields in a one - pot manner, by using Fe2O3, Co2O3 as catalyst, with molecular oxygen in the presence of valeraldehyde under mild conditions. The method is safer and very convenient, compared with the traditional oxdizing reagents. |
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| Keywords: | phenyl sulfide transition metal salts molecular oxygen aldehyde selective oxidation |
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