含杂原子杯芳烃的合成研究进展

综述了含杂原子杯芳烃的结构、命名方法、合成方法等方面的研究进展.指出在超分子化学领域,杯芳烃骨架结构的改变是杯芳烃研究的热点之一;与传统杯芳烃相比,在杯芳烃分子骨架中引入桥联杂原子或芳杂环后,不仅使得其在结构和分子识别方面产生新颖变化,而且使得其合成方法也发生巨大改变.

Research progress in synthesis of calixarenes containing heterogeneous atoms

A review is provided of the research progress in structure, nomenclature and synthetic methods of calixarenes containing heterogeneous atoms. It is pointed out that, in the field of supramolecular chemistry concerning calixarenes, altering backbone structure of vari- ous calixarenes is one of the hotspots. As compared with conventional calixarenes, introducing heterogeneous atoms as bridging fragments or heteroaromatics into the molecular backbone of calixarenes not only causes drastic differences in molecular structure and molecular recognition but also leads to great changes in methods for synthesizing new calixarenes.