| 四氮杂杯[2]芳烃[2]三嗪的合成及其叠氮化 |
| |
| 引用本文： | 郑林娟,曹端林,胡志勇,邵徽旺.四氮杂杯[2]芳烃[2]三嗪的合成及其叠氮化[J].化学研究,2008,19(2):28-30. |
| |
| 作者姓名： | 郑林娟 曹端林 胡志勇 邵徽旺 |
| |
| 作者单位： | 中北大学,化工与环境学院,山西,太原,030051 |
| |
| 摘 要： | 以简单易得的原料、在温和的条件下高产率地合成了氮原子桥连杯2]芳烃2]三嗪化合物．室温下，碳酸钾为缚酸剂，利用三聚氯氰和对苯二胺的亲核取代反应合成主体，并首次将其叠氮化，反应温度为40℃．产物通过元素分析，红外光谱和氢谱对其结构进行表征．从而验证了合成路线的可行性，并得出了较佳的工艺条件．
|
| 关 键 词： | 超分子化学 杂原子杯芳烃 三聚氯氰 合成 |
Synthesis and Azidotion Reaction of Tetraazacalix[2]arene[2]triazine |
| |
| ZHENG Lin-juan,CAO Duan-lin,HU Zhi-yong,SHAO Hui-wang.Synthesis and Azidotion Reaction of Tetraazacalix[2]arene[2]triazine[J].Chemical Research,2008,19(2):28-30. |
| |
| Authors: | ZHENG Lin-juan CAO Duan-lin HU Zhi-yong SHAO Hui-wang |
| |
| Institution: | (College of Chemical Engineering and Environment, North University of China, Taiyuan 030051, Shanxi, China) |
| |
| Abstract: | Aza-bridged calix2]arene2]triazine was synthesized through cheap raw material with an unusually high yielding and efficiency in gentle condition.Tetraazacalix2]arene2]triazine was synthesized by pphenylenediamine and cyanuric chloride at room temperature with potassium carbonate as neutralizing reagent.The azidotion was taken place by sodium azide and tetraazacalix2]arene2]triazine at 40 ℃.The product was characterized by melting point,IR,elemental analysis and 1H NMR.Consequently this synthetic route is feasible,and the offective technology condition is abtained. |
| |
| Keywords: | supermolecules heteroatom-bridged calixarenes cyanuric chloride synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
