| 三维超分子Ni(Ⅱ)Schiff碱配合物的合成与晶体结构 |
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| 引用本文： | 党娟,孔凡红,刘宝林,陶偌偈.三维超分子Ni(Ⅱ)Schiff碱配合物的合成与晶体结构[J].化学研究,2011,22(1):49-52. |
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| 作者姓名： | 党娟 孔凡红 刘宝林 陶偌偈 |
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| 作者单位： | 1. 河南大学化学化工学院,河南,开封,475004
2. 河南大学化学化工学院,河南,开封,475004;河南大学基础实验教学中心,河南,开封,475004 |
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| 基金项目： | 河南省教育厅资助项目，河南省科技厅资助项目 |
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| 摘 要： | 合成了新的三维超分子化合物NiL2]·H2O(HL为3-醛基水杨酸单缩乙二胺),并借助红外光谱、元素分析、热重分析和X射线单晶衍射等测试手段对其结构进行了表征.单晶结构解析结果表明,标题化合物属于单斜晶系,C2/c空间群,晶胞参数为:a=1.144 5(11)nm,b=1.914 4(19)nm,c=0.978 3(...
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| 关 键 词： | Schiff碱 Ni(Ⅱ)配合物 合成 晶体结构 |
Synthesis and crystal structure of three-dimensional supermolecular complex of Ni(Ⅱ)Schiff base |
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| DANG Juan,KONG Fan-hong,LIU Bao-lin,TAO Ruo-jie.Synthesis and crystal structure of three-dimensional supermolecular complex of Ni(Ⅱ)Schiff base[J].Chemical Research,2011,22(1):49-52. |
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| Authors: | DANG Juan KONG Fan-hong LIU Bao-lin TAO Ruo-jie |
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| Institution: | 1.College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,Henan,China;2.Basic Experiment Teaching Center,Henan University,Kaifeng 475004,Henan,China) |
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| Abstract: | A new three dimensional supermolecular compound ／·H2O was synthesized（HL refers to 3-formyl-salicylic acid monocondensed ethylenediamine）.The structure of the product was characterized by means of infrared spectrometry,elemental analysis,thermogravimetric analysis and X-ray single-crystal diffraction.Results indicate that title compound belongs to monoclinic system,space group C2/c with lattice parameters a = 1.144 5（11） nm,b = 1.914 4（19） nm,c = 0.978 3（10） nm,β = 99.876 2（2）°,V = 2.118 3（4） nm3,Z = 4,Dc = 1.540 g/cm3,μ = 3.496 mm-1,F（000） = 1 024,R1 = 0.026 5,wR2 = 0.062 4.Nickel（Ⅱ） ion in the compound is six-coordinated in octahedral configuration,and three-dimensional network structure is formed through the intermolecular hydrogen bonds. |
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| Keywords: | Schiff base nickel（Ⅱ） complex synthesis crystal structure |
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