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| 丙烯酸β-羟丙酯/乙烯基吡咯烷酮水凝胶的合成和热敏行为的研究 | |
| 引用本文： | 高青雨,张玉娟,刘瑞雪,石家华,崔元臣,俞贤达.丙烯酸β-羟丙酯/乙烯基吡咯烷酮水凝胶的合成和热敏行为的研究[J].化学研究,2000,11(2):23-27. |
| 作者姓名： | 高青雨 张玉娟 刘瑞雪 石家华 崔元臣 俞贤达 |
| 作者单位： | 1. 中国科学院兰州化学物理研究所兰州730000 河南大学化学化工学院开封475001 2. 河南大学化学化工学院开封475001 3. 中国科学院兰州化学物理研究所兰州730000 |
| 基金项目： | 河南省自然科学基金，991190312， |
| 摘 要： | 用自由基共聚法合成了一系列 β -羟丙酯 ( β -HPAT)和乙烯基吡咯烷酮 (NVP)的共聚物及其水凝胶。发现共聚物的水溶液有敏锐的温敏行为 ,最低汇溶温度 (LCST)随NVP含量的增加而升高 ,随着反应单体总浓度的增加 ,相变敏锐性下降且LCST也随之下降。通过考察水凝胶的溶胀率 (SR) ,发现共聚凝胶在适当的单体浓度 ,交联剂浓度和较宽的单体浓度配比范围内 ,有较灵敏的温敏行为。 |
| 关 键 词： | 丙烯酸β-羟丙酯 乙烯基吡咯烷酮 自由基共聚 温敏水凝胶 |
| 文章编号： | 1008-1011(2000)02-0023-05 |
| 修稿时间： | 2000年1月15日 |
Synthesis and Characterization of Temperature Sensitive Copolymer of β-HPAT/NVP |
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| Gao Qingyu ,Zhang Yujuan ,Liu Ruixue ,Shi Jiahua ,Cui Yuanchen ,Yu Xianda.Synthesis and Characterization of Temperature Sensitive Copolymer of β-HPAT/NVP[J].Chemical Research,2000,11(2):23-27. | |
| Authors: | Gao Qingyu Zhang Yujuan Liu Ruixue Shi Jiahua Cui Yuanchen Yu Xianda |
| Institution: | Gao Qingyu 1,2,Zhang Yujuan 2,Liu Ruixue 2,Shi Jiahua 2,Cui Yuanchen 2,Yu Xianda 1 |
| Abstract: | In this study, random copolymer of β -HPAT and NVP poly( β -HPAT-co-NVP) was prepared by radical copolymerization. The hydrogel of β -HPAT/NVP obtained by changing the initial β HPAT/NVP mol ratio, total monomer, and cross linker concentration has different thermoresponsive properties. The copolymer with wide range of β -HPAT/NVP mol ratio has sensitively thermoresponsive character. The result shows that cross linker concentration has greater effect on the swelling ratio (SR), the total monomer concentration has greater effect on the sensitivity of thermoresponsity, and the LCST of copolymer is decided by the β -HPAT/NVP mol ratio. |
| Keywords: | hydropropyl acrylate N-vinyl pyrrolidone radical polymerization thermoresponsive hydrogel |
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