六亚甲基四胺锑(Ⅲ)、铋(Ⅲ)配合物的固相合成与表征

通过固相反应,合成了新的配合物六亚甲基四胺锑(Ⅲ)、铋(Ⅲ):SbCl3(C6H12N4)2·H2O(1)、BiCl3(C6H12N4)2·H2O(2).经元素分析、X 射线粉末衍射、远红外光谱和差热 热重分析进行表征,确定了配合物的组成和结构.对XRD谱指标化,确定其晶系和晶胞参数.SbCl3(C6H12N4)2·H2O(1):a=1.2490nm,b=1.4583nm,c=1.6870nm,β=91.78°,V=3.0706nm3;BiCl3(C6H12N4)2·H2O(2):a=1.3250nm,b=1.3889nm,c=1.7449nm,β=98.94°,V=3.1725nm3.

Solid Phase Synthesis and Characterization of Antimony(Ⅲ) and Bismuth(Ⅲ) Hexamethylenetetramine Complexes

Hexamethylenetetramine complexes of antimony(Ⅲ) and bismuth(Ⅲ), SbCl3 (C6H12N4)2·H2O (1) and BiCl3 (C6H12N4)2·H2O (2) were synthesized by the solid phase reaction. The complexes have been characterized by elemental analysis, IR spectra, X ray powder diffraction and TG DTA. Both complexes belong to monoclinic system and the lattice parameters are a=1.249 0 nm,b=1.458 3 nm,c=1.687 0 nm,β=91.78°,V=3.070 6 nm3 for SbCl3(C6H12N4)2·H2O;a=1.325 0 nm,b=1.388 9 nm,c=1.744 9 nm,β=98.94°,V=3.172 5 nm3 for BiCl3(C6H12N4)2·H2O.