| 含噻吩杂环Schiff碱及其配合物的合成与发光性质 |
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| 引用本文： | 陈延民,陈玲兰,蔡伟正,刘金花,何雪倩,张琼如.含噻吩杂环Schiff碱及其配合物的合成与发光性质[J].化学研究,2014(5):474-478. |
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| 作者姓名： | 陈延民 陈玲兰 蔡伟正 刘金花 何雪倩 张琼如 |
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| 作者单位： | 泉州师范学院化学与生命科学学院,福建泉州362000 |
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| 基金项目： | 泉州师范学院学科建设资金资助,2013年国家级大学生创新创业训练计划项目（201310399018）. |
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| 摘 要： | 在热乙醇中合成了2-乙酰基噻吩缩异烟酰肼及其与Cd(II)、Cu(II)和Zn(II)形成的三种配合物;利用元素分析、摩尔电导测定,以及红外光谱、紫外光谱和热分析确定了合成产物的组成和结构,并测定了配合物的组成及发光性质.结果表明,酰肼的配位方式的不同导致配合物呈现不同的发光性质.
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| 关 键 词： | 2-乙酰基噻吩缩异烟酰肼 Schiff碱 配合物 合成 发光性质 |
Synthesis and luminescent properties of thienyl Schiff base and its coordination compounds |
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| CHEN Yanmin,CHEN Linglan,CAI Weizheng,LIU Jinhua,HE Xueqian,ZHANG Qiongru.Synthesis and luminescent properties of thienyl Schiff base and its coordination compounds[J].Chemical Research,2014(5):474-478. |
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| Authors: | CHEN Yanmin CHEN Linglan CAI Weizheng LIU Jinhua HE Xueqian ZHANG Qiongru |
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| Institution: | (College of Chemistry and Life Science, Quanzhou Normal University, Quanzhou 362000, Fujian, China) |
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| Abstract: | 2-acetylthiophene-N-isonicotinoylhydrazone and its complexes with Cd （II）,Cu （II）, and Zn （II）were synthesized in hot ethanol.The composition and structure of as-synthesized products were analyzed based on elemental analysis and molar conductivity measurement as well as infrared spectrometric,ultraviolet spectrometric and thermogravimetric analyses.Mo-reover,the luminescent properties of as-synthesized products were measured.Results indicate that the luminescent properties of the as-synthesized coordination compounds vary with varying coordination modes of the hydrazide. |
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| Keywords: | 2-acetylthiophene-N-isonicotinylhydrazide Schiff base coordination compound synthesis luminescent properties |
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