| 有机热稳定剂三(十二硫醇)锑的合成 |
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| 引用本文： | 庞爱红,郑波,曹阳,顾建胜.有机热稳定剂三(十二硫醇)锑的合成[J].化学研究,2005,16(1):26-28. |
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| 作者姓名： | 庞爱红 郑波 曹阳 顾建胜 |
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| 作者单位： | 苏州大学,化学化工学院,江苏,苏州,215006;苏州大学,化学化工学院,江苏,苏州,215006;苏州大学,化学化工学院,江苏,苏州,215006;苏州大学,化学化工学院,江苏,苏州,215006 |
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| 摘 要： | 以牺牲锑阳极法电解得到的活性金属锑粉Sb* (10 ~15nm)为原料,直接与十二烷基硫醇反应制得三(十二硫醇)锑,产品经元素分析和IR测定进行表征.较佳的合成反应条件为:反应温度为 80~90℃;物料配比为n(十二烷基硫醇)∶n(锑) =30∶1;操作过程简单,基本无污染.
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| 关 键 词： | 热稳定剂 三(十二硫醇)锑 有机锑 |
| 文章编号： | 1008-1011(2005)01-0026-03 |
| 修稿时间： | 2004年9月21日 |
Synthesis of Organic Thermal Stabilizer:Antimony tri(n-dodecanethiol) |
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| PANG Ai-Hong,ZHENG Bo,CAO Yang,GU Jian-Sheng.Synthesis of Organic Thermal Stabilizer:Antimony tri(n-dodecanethiol)[J].Chemical Research,2005,16(1):26-28. |
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| Authors: | PANG Ai-Hong ZHENG Bo CAO Yang GU Jian-Sheng |
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| Institution: | PANG Ai-hong,ZHENG Bo,CAO Yang,GU Jian-sheng~* |
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| Abstract: | Ultrafine active antimony Sb~*(10～15 nm), which was prepared by electrolyzation in HCl media, was directly reacted with n-dodecanethiol to get antimony tri(n-dodecanethiol). The product was characterized by elemental analysis and IR spectra. The optimal reaction conditions were that reaction temperature was 80～90 ℃ and the mole ratio of n-dodecanethiol to antimony was 30∶1. The synthetical process is simple without contamination. |
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| Keywords: | stabilizer antimony tri(n-dodecanethiol) organic antimony |
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