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| 碳负载钯催化剂对Heck反应的催化性能 | |
| 引用本文： | 左春山,徐启杰,时文中,崔元臣.碳负载钯催化剂对Heck反应的催化性能[J].化学研究,2013(5):479-482,488. |
| 作者姓名： | 左春山 徐启杰 时文中 崔元臣 |
| 作者单位： | 1. 黄淮学院 化学化工系,河南 驻马店,463000 2. 黄淮学院 化学化工系，河南 驻马店 463000; 河南大学 特种功能材料重点实验室，河南 开封 475004 3. 河南大学 特种功能材料重点实验室,河南 开封,475004 |
| 基金项目： | 河南省科技发展计划项目(0624270040，092300410121，112300410184)． |
| 摘 要： | 研究了钯碳催化剂对芳基卤和取代芳基卤与丙烯酸和苯乙烯的Heck芳基化反应的催化性能.结果表明:在反应温度为80℃、反应时间为8h、四丁基溴化铵(TBABr)作为溶剂和三丁胺作为碱的条件下,钯碳催化剂对不同取代芳基卤与丙烯酸和苯乙烯的Heck芳基化反应具有良好的催化性能,产物收率在80%以上. |
| 关 键 词： | 碳负载Pd催化剂 Heck反应 催化性能 |
Catalytic performance of carbon supported palladium catalyst for Heck reaction |
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| ZUO Chunshan , XU Qijie , SHI Wenzhong , CUI Yuanchen.Catalytic performance of carbon supported palladium catalyst for Heck reaction[J].Chemical Research,2013(5):479-482,488. | |
| Authors: | ZUO Chunshan XU Qijie SHI Wenzhong CUI Yuanchen |
| Institution: | ZUO Chun-shan;XU Qi-jie;SHI Wen-zhong;CUI Yuan-chen;Department of Chemistry & Chemical Engineering,Huanghuai University;Key Laboratory for Special Functional Materials,Henan University; |
| Abstract: | The catalytic performance of carbon supported palladium catalyst for the Heck reac- tion of phenyl halide and substituted phenyl halide with acrylic acid or styrene was studied. Re- sults show that carbon supported palladium catalyst can effectively catalyze the investigated Heck reactions under a temperature of 80 ℃ and a reaction duration of 8 h in the presence of tetrabutylammonium bromide solvent and tributylamine alkali, affording a yield of over 80%. Besides, it can also well catalyze the Heck reaction of substituted phenyl halide with acrylic acid or styrene. |
| Keywords: | carbon supported palladium catalyst Heck reaction catalytic performance |
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