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Polypropylene fabrics padded with microencapsulated ammonium phosphate: Effect of the shell structure on the thermal stability and fire performance
Authors:I Vroman  S Giraud  S Bourbigot
Institution:a Groupe de Recherches en Science Pour l’Ingénieur (GRESPI), EA4301, Ecole Supérieure d’Emballage et de Conditionnement, BP 1026 Reims Cedex 2, France
b Laboratoire de GEnie et Matériaux TEXtiles (GEMTEX), UPRES EA 2161, Ecole Nationale Supérieure des Arts et Industries Textiles, BP 59056 Roubaix Cedex, France
c Laboratoire de Génie des Procédés d’Elaboration des Revêtements Fonctionnels (PERF), UPRES EA 1040, Ecole Nationale Supérieure de Chimie de Lille, Villeneuve d’Ascq, France
Abstract:Three types of microcapsules of di-ammonium hydrogen phosphate (DAHP) with different polymeric shells were evaluated as flame retardants in commercial polyurea padding for textiles. Encapsulated FR agent has the advantage of being compatible with the polymer matrix. The thermal degradation for the three types of DAHP microcapsules shows that our microcapsules act as intumescent fire retardants. The reaction to fire of polypropylene fabrics padded with FR polyurea loaded with neat DAHP or microencapsulated DAHP was studied with the cone calorimeter as a fire model.
Keywords:Flame retardant  Phosphate  Microencapsulation  Thermal degradation  Textile  Padding
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