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Electrochemistry of polyaminobenzenes: Part 2. Oxidation of hexakis(dimethylamino)benzene at high potentials
Institution:1. Institut für Organische Chemie, Auf der Morgenstelle 18, D-72076 Tübingen, Germany;2. Departamento de Quı́mica Orgánica, Edificio de Farmacia, Universidad de Alcalá, Carretera de Barcelona, Km. 33.600, Alcalá de Henares, 28871 Madrid, Spain;1. Department of Food Science and Technology, School of Agriculture, Shiraz University, Shiraz, Iran;2. Department of Food Technology, Engineering and Nutrition, Faculty of Engineering, Lund University, Lund, Sweden;3. Enhanced Oil Recovery (EOR) Research Center, School of Chemical and Petroleum Engineering, Shiraz University, Shiraz, Iran;1. School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan, 430070, PR China;2. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, PR China;1. Speech and Language Laboratory, the Australian National University, Canberra, Australia;2. Linguistics Program, School of Culture, History and Language, College of Asia and the Pacific, the Australian National University, Building #110, Canberra, ACT 2600, Australia;1. Leibniz-Institut für Wissensmedien, Germany;2. Amsterdam School of Communication Research (ASCoR), University of Amsterdam, the Netherlands;3. University of Tübingen, Germany
Abstract:Hexakis(dimethylamino)benzene is electrochemically oxidized to species with oxidation states higher than that of a tetracation. The reaction is followed by cyclic voltammetry. A mechanistic scheme of the electrode reaction mechanism is proposed. Computer simulations of cyclic voltammograms at scan rates between 0.02 and 50 V s−1 allow the estimation of reaction parameters. A comparison of the potentials for the redox steps with data by other authors supports a re-interpretation of their results.
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