| Ca+-Pyridine络合物的光解反应 |
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| 引用本文： | 王东升,韩克利,杨士和. Ca+-Pyridine络合物的光解反应[J]. 化学物理学报(中文版), 2006, 19(2): 123-125. DOI: 10.1360/cjcp2006.19(2).123.3 |
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| 作者姓名： | 王东升 韩克利 杨士和 |
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| 作者单位： | 中国科学院大连化学物理研究所分子反应动力学国家重点实验室,大连,116023;香港科技大学化学系,香港 |
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| 摘 要： |
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| 关 键 词： | 络合物 光解 行为光谱 |
Photo-induced Intra-complex Reactions in Ca+-Pyridine |
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| Dong-sheng Wang,Ke-li Han,Shi-he Yang. Photo-induced Intra-complex Reactions in Ca+-Pyridine[J]. Chinese Journal of Chemical Physics, 2006, 19(2): 123-125. DOI: 10.1360/cjcp2006.19(2).123.3 |
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| Authors: | Dong-sheng Wang Ke-li Han Shi-he Yang |
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| Abstract: | Photodissociation spectra of Ca+-pyridine complex was obtained by reflectron time of flight spectrum (RTOF). Two channels were found from difference photodissociation spectra, one was non-reactive Ca+ cation separation channel, the other one was active channel for product Ca+NH2. Product Ca+ was dominant in the whole region studied and the only product in 530-590 nm region, reactive product Ca+NH2 shared a little present in whole products. Action spectrum as a function of photolysis laser wavelength shows appearance peaks relevant to transitions of complex. Branching ratio supports the information of photodissociation too. |
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| Keywords: | Complex Photodissociation Action spectrum |
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