Low-temperature Catalytic Reduction of Nitrogen Monoxide with Carbon Monoxide on Copper Iron and Copper Cobalt Composite Oxides |
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Authors: | Jun-sheng Shu Wen-shui Xia You-jin Zhang Tao Cheng Min-rui Gao |
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Abstract: | Copper iron composite oxides (CuO/Fe2O3) and copper cobalt composite oxides (CuO/Co3O4) for the catalytic reduction of NO with CO at low temperature were prepared by co-precipitation. The catalytic activity and thermal stability of the catalysts were evaluated by a microreactor-GC system. The 100% conversion temperatures of NO are 80 oC for CuO/Fe2O3 and 90 oC for CuO/Co3O4. The catalysts possess high catalytic activity and favorable thermal stability for NO reduction with CO in a wide temperature range and long time range. A systematic study of the molar ratios of the reactants, the volume of NaOH, aging time, and calcination temperature/time was carried out to investigate the influence preparation conditions on the catalytic activity of the catalysts. |
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Keywords: | CuO/Fe2O3 CuO/Co3O4 NO reduction Catalytic activity Thermal stability |
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