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二氧化钒纳米棒的相变行为
引用本文:罗莹,;李明,;李广海.二氧化钒纳米棒的相变行为[J].化学物理学报(中文版),2014(4):471-474.
作者姓名:罗莹  ;李明  ;李广海
作者单位:[1]中国科学院材料物理重点实验室,安徽省纳米材料和纳米技术重点实验室,中国科学院固体物趣研究所,合肥230031; [2]中国科学技术大学,合肥230026
基金项目:V. ACKNOWLEDGMENTS This work was financially Natural Science Foundation supported by the National of China (No.51372250).
摘    要:研究了VO2(M)纳米棒的金属绝缘体相变(MIT)行为.在VO2(M)纳米棒的DSC分析曲线上发现了两个MIT,分别位于低温和高温区.低温MIT总是伴随出现VO2(B)纳米棒,而独立的高温MIT出现在纯VO2(M)纳米棒.分析和讨论了这两个MIT的机制.

关 键 词:二氧化钒  纲采棒  金属绝缘体相变

Phase Transition Behaviour of VO2 Nanorods
Institution:Ying Luo, Ming Li, Guang-hai Li(1. Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China 2. University of Science and Technology of China, Hefei 230025, China)
Abstract:The metal-insulator transition (MIT) of VO2 (M) nanorods was studied. It was found that there were two MITs in the differential scanning calorimetry (DSC) curves of the VO2(M) nanorods, one situated at low temperature from -3 ℃ to 19 ℃ and the other was at high temperature of 65-74℃. The low temperature MIT was always accompanied with VO2(B) nanorods, and the high temperature MIT existed singly only in pure VO2(M) nanorods. The mechanisms of these two MITs were analyzed and discussed.
Keywords:Vanadium dioxide  Nanorod  Metal-insulator transition
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