| 卤素双原子分子部分电子态的完全振动能谱和离解能 |
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| 引用本文： | 渠双双,孙卫国,王宇杰,樊群超.卤素双原子分子部分电子态的完全振动能谱和离解能[J].物理化学学报,2009,25(1):13-18. |
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| 作者姓名： | 渠双双 孙卫国 王宇杰 樊群超 |
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| 作者单位： | Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, P. R. China |
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| 基金项目： | 国家自然科学基金，教育部科学基金 |
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| 摘 要： | 用代数方法(AM)可以获得双原子分子包含最高振动能级在内的所有高阶振动能级的完全振动能谱; 基于Leroy和Bernstein的能级表达式, 研究了卤族元素双原子分子Cl2-A’3∏(2u)、Br2-X1∑+g和I2-0+u电子态的完全振动能谱和离解能, 得到的理论结果与实验符合得很好.
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| 关 键 词： | 代数方法 振动能级 离解能 卤素分子 双原子分子 |
| 收稿时间： | 2008-07-04 |
| 修稿时间： | 2008-09-26 |
Full Vibrational Energy Spectra and Dissociation Energies for Some Electronic States of Diatomic Halogen Molecules |
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| QU Shuang-Shuang,SUN Wei-Guo,WANG Yu-Jie,FAN Qun-Chao.Full Vibrational Energy Spectra and Dissociation Energies for Some Electronic States of Diatomic Halogen Molecules[J].Acta Physico-Chimica Sinica,2009,25(1):13-18. |
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| Authors: | QU Shuang-Shuang SUN Wei-Guo WANG Yu-Jie FAN Qun-Chao |
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| Institution: | Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, P. R. China |
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| Abstract: | The algebraic method (AM) and a new formula for dissociation energy were used to study full vibrational energies {EAMυ} and dissociation energies DAMe of three electronic states Cl2-A’3∏(2u), Br2-X1∑+g, and I2-0+uof diatomic halogen molecules. The obtained results are in agreement with known experimental data. |
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| Keywords: | Algebraic Method Vibrational energy Dissociation energy Halogen molecule Diatomic molecule |
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