| 聚电解质和表面活性剂混合体系中多价金属离子诱导的囊泡聚集 |
| |
| 引用本文： | 么敬霞,赵颖,黄建滨.聚电解质和表面活性剂混合体系中多价金属离子诱导的囊泡聚集[J].物理化学学报,2006,22(8):913-916. |
| |
| 作者姓名： | 么敬霞 赵颖 黄建滨 |
| |
| 作者单位： | State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China |
| |
| 基金项目： | 国家自然科学基金;高等学校博士学科点专项科研项目 |
| |
| 摘 要： | 利用浊度和电镜观察等方法研究了水解的苯乙烯-马来酸酐共聚物(SMA)和十二烷基三乙基溴化铵(DEAB)混合体系中多价金属离子诱导的囊泡聚集现象. 提出了关于多价金属离子诱导囊泡聚集的机理.
|
| 关 键 词： | 囊泡 囊泡聚集 多价金属离子 聚电解质鄄表面活性剂混合体系 |
| 收稿时间： | 2006-04-28 |
| 修稿时间： | 2006-05-19 |
Multivalent Metal Ion Induced Vesicle Aggregation in Aqueous Polyelectrolyte-surfactant System |
| |
| YAO,Jing-Xia,ZHAO,Ying,HUANG,Jian-Bin.Multivalent Metal Ion Induced Vesicle Aggregation in Aqueous Polyelectrolyte-surfactant System[J].Acta Physico-Chimica Sinica,2006,22(8):913-916. |
| |
| Authors: | YAO Jing-Xia ZHAO Ying HUANG Jian-Bin |
| |
| Institution: | State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China |
| |
| Abstract: | The vesicle aggregation induced by multivalent metal ions in the mixed system of polyelectrolyte(hydrolyzed random copolymer of maleic anhydride-styrene, SMA)-surfactant(dodecyltriethylammonium bromide, DEAB) was investigated through transmission electron microscopy (TEM) observation and turbidity measurement. It was found that a small quantity of Ca2+ (in the magnitude of 10-4 mol·L-1) can induce vesicle aggregation. Adding EDTA can dissociate the vesicle aggregation. Further investigation suggested that the vesicle aggregation followed the salt-linkage mechanism. |
| |
| Keywords: | Vesicles Vesicle aggregation Multivalent metal ion Polyelectrolyte-surfactant system |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
