| 添加Fe对Pt/KL沸石芳构化及抗硫性能的影响 |
| |
| 引用本文： | 郑坚,董家禄,须沁华.添加Fe对Pt/KL沸石芳构化及抗硫性能的影响[J].物理化学学报,1997,13(6):573-576. |
| |
| 作者姓名： | 郑坚 董家禄 须沁华 |
| |
| 作者单位： | Department of Chemistry,Nanjing University,Nanjing 210093 |
| |
| 摘 要： | Pt／KL沸五催化剂对正己烷的芳构化反应具有特别高的活性和选择性，但是它对原料中硫的存在非常敏感，要求合硫量小平川’，而工业催化剂的硫含量允许10’．这使得Pt／KL佛石催化剂一直未能工业化山．近年来，文献上开始出现了一些KL佛石上负载双金属的研究工作［’－’1．通过
|
| 关 键 词： | Pt/Fe双金属 KL沸石 正已烷芳构化 硫中毒 |
| 收稿时间： | 1996-07-08 |
| 修稿时间： | 1997-03-05 |
The Influence of Fe on the Aromatization Reactivity and Sulphur-resistance of Pt/KL Zeolite |
| |
| Zheng Jian, Dong Jialu, Xu Qinhua.The Influence of Fe on the Aromatization Reactivity and Sulphur-resistance of Pt/KL Zeolite[J].Acta Physico-Chimica Sinica,1997,13(6):573-576. |
| |
| Authors: | Zheng Jian Dong Jialu Xu Qinhua |
| |
| Institution: | Department of Chemistry,Nanjing University,Nanjing 210093 |
| |
| Abstract: | The influence of second metal component (Fc) on Pt/KL zeolie catalyst was investi-gated. The catalytic properties of Pt-Fe/KL zeolite varied as the amount of Fe. When the amount of Fe was 0.3 % (mass fraction), the catalyst was found to show both excellent n-hexane aromati-zation reactivity and higher ability for sulphur-resistance. The dispersion of Pt particles was also found to be better in this bimetallic catalyst, whereas the electron state of Pt particles as indicated by CO-FTIR was nlodified to be more electron-deficient than that of Pt/KL zeolite, which made the bimetallic Pt-Fe/KL more tolerant to sulphur poisoning. |
| |
| Keywords: | Pt-Fe bimetallic supported catalyst KL zeolite n-hexane aromatization Sulphur-resistance |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
