| 铜(II)-5-取代邻菲啰啉-二氧四胺大环三元体系的稳定性研究 |
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| 引用本文： | 林华宽,朱守荣,Appolin,B.Kondiano,寇福平,陈荣悌.铜(II)-5-取代邻菲啰啉-二氧四胺大环三元体系的稳定性研究[J].物理化学学报,1997,13(5):417-424. |
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| 作者姓名： | 林华宽 朱守荣 Appolin B.Kondiano 寇福平 陈荣悌 |
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| 作者单位： | Department of Chemistry,Nankai University,Tianjin 300071 |
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| 摘 要： |
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| 关 键 词： | 配合物的稳定性 侧基二氧四胺大环配体 5-取代-1 10-邻菲啰啉 铜(II) |
| 收稿时间： | 1996-10-07 |
| 修稿时间： | 1996-12-05 |
Study on Stability of Copper(II)-5-Substituted-1,10-Phenanthrolines-Dioxotraamines Macrocycles Ternary Systems |
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| Lin Hua-Kuan,Zhu Shou-Rong,Appolin,B.Kondiano,Kou Fu-Ping,Chen Rong-Ti.Study on Stability of Copper(II)-5-Substituted-1,10-Phenanthrolines-Dioxotraamines Macrocycles Ternary Systems[J].Acta Physico-Chimica Sinica,1997,13(5):417-424. |
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| Authors: | Lin Hua-Kuan Zhu Shou-Rong Appolin BKondiano Kou Fu-Ping Chen Rong-Ti |
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| Institution: | Department of Chemistry,Nankai University,Tianjin 300071 |
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| Abstract: | The stability of copper (Ⅱ)-13-(2'-Hydroxy-3',5'-substituted benzyl)-1,4,8,11-tetraazacyclotetradecane-12, 14-dione(RTADO-14) binary complex compounds and of copper (Ⅱ)-5-substituted-1,10-phenanthrolines(R'TADO)-RTADO-14 ternary complex compounds was studied by means of pH titration method at 25.0±0.1 ℃ and I=0.1mol?dm-3KNO3. The formation constants of binary and ternary complexes were obtained. The structures of the binary and ternary complxes and the effects fo substituents on macrocyclic ligands and on R'Phen were also discussed. |
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| Keywords: | Stability of complexes Functionalized macrocyclic dioxotetraamines 5-Substituted-1 10-phenanthrolines Copper(II) |
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