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具有多体效应的胶体聚团的特征
引用本文:李敬生,P.Mark Rodger.具有多体效应的胶体聚团的特征[J].物理化学学报,1997,13(1):28-35.
作者姓名:李敬生  P.Mark Rodger
作者单位:Department of Metallurgy,Xi'an University of Architecture and Technology,Dept.of Chem,Univ,of Reading,U.K
摘    要:考察了多体效应(用Stutton-Chen势,SC)对胶体聚团的影响并与双体(LJ)势下的结果作了比较。研究表明,SC和LJ势下簇团的性质有其相似的一面,如:随着剪应力的增加,系统里颗粒的平均势能增加,而每个簇团的颗粒数减少;在较强的剪应力场里,簇团沿剪应力方向(X轴)被明显拉长且其主轴偏离X轴等。但它们间的差异也是明显的,在剪应力下SC系统内颗粒排列得更合理,从而使得平均位能比LJ系统低约1-3

关 键 词:多体效应  胶体  计算机模拟  
收稿时间:1996-05-31
修稿时间:1996-07-10

Characteristics of Colloidal Aggregates with Many-body Effect
Li Jingsheng.Characteristics of Colloidal Aggregates with Many-body Effect[J].Acta Physico-Chimica Sinica,1997,13(1):28-35.
Authors:Li Jingsheng
Institution:Department of Metallurgy,Xi'an University of Architecture and Technology|Dept.of Chem,Univ,of Reading,U.K
Abstract:Effects of many-body (by Suttoll-Chen Potential, SC) on colloidal aggregates have have been exammed and compared with that ot two-body (by Lennard-Jones potential, LJ)Some characteristics were similar in both SC and LJ systems such as potential energy increased, and the number of particles in a cluster decreased wtih increasing shear rates; clusters were stretched remarkably in shear (X axis) direction and the longest axis of clusters deviated from X axis under stronger shear held; etc. Their differences were also obvious : arrangement of particles in SC system wasmore reasonable than in LJ system so that the potential energy in SC system was lower 1-3 dimensionless energy umts, thereby clusters in SC system were closer and their fractal dimension higher;dependent of petential energy for particles, average cluster size and fractal dimension on shearrates was weaker in SC than in LJ systems; morphologies of clusters were occasionally changed to some extent.
Keywords:Many-body effect  Colloids  Computer simulation
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