| Ba(1S)+N2O反应的化学发光偏振研究 |
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| 引用本文： | 王志宇,何国钟,楼南泉.Ba(1S)+N2O反应的化学发光偏振研究[J].物理化学学报,1988,4(6):653-656. |
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| 作者姓名： | 王志宇 何国钟 楼南泉 |
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| 作者单位： | Dalian Institute of Chemical Physics; CAS |
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| 摘 要： |
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| 收稿时间： | 1987-04-20 |
| 修稿时间： | 1988-01-16 |
CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(1S) +N2O REACTION |
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| Wang Zhiyu,He Guozhong,Lou Nanquan.CHEMILUMINESCENT POLARIZATION STUDIES OF Ba(1S) +N2O REACTION[J].Acta Physico-Chimica Sinica,1988,4(6):653-656. |
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| Authors: | Wang Zhiyu He Guozhong Lou Nanquan |
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| Institution: | Dalian Institute of Chemical Physics; CAS |
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| Abstract: | The variation of ehemiluminescent polarization for reaction Ba(~1S)+N_2O with respect to the Ba beam temperature or the average collision energy E_(rtr) was studied under the single collision condition on beam-gas apparatus. If E_(rtr)<0.06 eV, the distribution of rotational angular momentum for product BaO, i.e. -, increased with the impact energy; while E_(rtr)>0.06 eV, - decreased with the E_(rtr). It is plausible to point out the corresponding relationship between the characteristics of the reaction potential surface and the conformation of the intermediate complexes. |
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