| 硫堇的电化学聚合及聚硫堇的性质 |
| |
| 引用本文： | 孔泳,穆绍林.硫堇的电化学聚合及聚硫堇的性质[J].物理化学学报,2001,17(4):295-299. |
| |
| 作者姓名： | 孔泳 穆绍林 |
| |
| 作者单位： | Department of Chemistry, School of Sciences,Yangzhou University,Yangzhou 225002 |
| |
| 基金项目： | 国家自然科学基金资助项目（20074027） |
| |
| 摘 要： | 使用循环伏安法实现了硫堇在酸性溶液中的电化学聚合.聚硫堇是一种蓝色物质，它的颜色能随电位迅速变化.在0.50 mol?dm－3 HCl 至pH 6.0的溶液中，聚硫堇具有很好的电化学可逆性、稳定性和快速传递电子的能力.测定了聚硫堇的可见光谱和红外光谱，根据红外光谱，提出了硫堇的电化学聚合机理的假设.
|
| 关 键 词： | 硫堇 电化学聚合 聚合物光谱 电化学性质 |
| 收稿时间： | 2000-07-25 |
| 修稿时间： | 2000年7月25日 |
Electrochemical
Polymerization of Thionine and Properties of Polythionine |
| |
| Kong Yong,Mu Shao-Lin.Electrochemical
Polymerization of Thionine and Properties of Polythionine[J].Acta Physico-Chimica Sinica,2001,17(4):295-299. |
| |
| Authors: | Kong Yong Mu Shao-Lin |
| |
| Institution: | Department of Chemistry, School of Sciences,Yangzhou University,Yangzhou 225002 |
| |
| Abstract: | The electrochemical polymerization of thionine in the aqueous acetic solution has been carried out using cyclic voltammetry. Polythionine is a blue material. Its color can be quickly changed by applied potential. Polythionine has a good electrochemical reversibility, stability and a fast charge transfer ability in the solution of 0.50 mol· dm－ 3 HCl to the solution of acetate of pH 6.0. Visible and FTIR spectra of polythionine have been presented in this paper. Based on FTIR spectra, a suggestion for mechanism of polymerization of thionine is presented. |
| |
| Keywords: | Thionine Electrochemical polymerization Spectra of polythionine Electrochemical properties |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
