| 一种新型的长光程薄层光谱电化学池 |
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| 引用本文： | 顾登平,张雪英,蒋殿录,马子川.一种新型的长光程薄层光谱电化学池[J].物理化学学报,1993,9(3):416-420. |
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| 作者姓名： | 顾登平 张雪英 蒋殿录 马子川 |
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| 作者单位： | Department of Chemistry, Hebei Normal University, Shijiazhuang 050016; Department of Chemistry, Hebei Normal College |
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| 摘 要： | 1 前言光谱电化学是近年来发展起来的一门新兴学科,是把光谱方法和电化学方法结合起来,可进行现场分析的技术.作者曾用夹心式薄层电解池研究过超常价态Ag(Ⅲ)、Cu(Ⅲ),大分子冠醚配合物电还原反应的机理.对于一般的薄层电解池,由于从薄层正面透光,主要有三点不足:(1)由薄层溶液厚度决定的短光程,使得溶液粒子的检测灵敏度较低;(2)光透电极既需要透光
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| 关 键 词： | 薄层光谱电化学池 光谱电化学 新型的光谱电化学池 |
| 收稿时间： | 1991-11-19 |
| 修稿时间： | 1992-07-01 |
A NEW TYPE OF THIN-LAYER SPECTROELECTROCHEMICAL CELL FOR LONG OPTICAL PATH LENGTH |
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| Gu Dengping Zhang Xueying.A NEW TYPE OF THIN-LAYER SPECTROELECTROCHEMICAL CELL FOR LONG OPTICAL PATH LENGTH[J].Acta Physico-Chimica Sinica,1993,9(3):416-420. |
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| Authors: | Gu Dengping Zhang Xueying |
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| Institution: | Department of Chemistry, Hebei Normal University, Shijiazhuang 050016; Department of Chemistry, Hebei Normal College |
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| Abstract: | Thin-layer transmission spectroelectrochemistry provides an in-situ analyticalmethod.Based on previous research,the authors design a new type of thin-layerspectroelectrochemical cell for long optical path length.The construction of the cellis considered to be simplel;it's operation convinent and sensitivity high,it can bewidely used.The optical and electrochemical responses of the cell is measured bythe ferrocyanide system,it's property is good and reliable. |
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| Keywords: | Thin-layer spectroelectrochermical cell Spectroelectrochcmistry Spectroelectrochimical cell of new type |
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