高比能钠离子电池预钠化技术研究进展

钠离子电池有望取代锂离子电池实现大规模储能应用。然而，储钠负极材料具有较低的初始库伦效率，制约了高比能钠离子电池的开发。预钠化技术被认为是补偿负极活性钠损失、提升电池能量密度的最直接有效的方法，对于钠离子电池的商业化应用具有重要意义。本文全面总结近年来预钠化技术的最新研究进展，包括短接法预钠化、电化学预钠化、钠金属物理预钠化、化学预钠化和正极补钠添加剂等，并从反应原理、安全性、可操作性、处理效率和可放大性等角度分析讨论现有各技术方案的优势及面临的挑战；着重介绍化学预钠化和正极补钠添加剂，这两类最具应用前景的预钠化技术的最新成果，进而从实用化角度深入探讨仍待解决的科学问题和技术难点。本文可为预钠化技术的进一步优化和高比能钠离子电池的开发提供思路。

Research Progress on Presodiation Strategies for High Energy Sodium-Ion Batteries

Lithium-ion batteries (LIBs) have attracted considerable attention owing to their high energy density and long cycle life. However, lithium resources have become scarcer with the rapid development of electric vehicles and smart grid technologies. Considering the inexpensive and abundant supply of sodium, sodium-ion batteries (SIBs) are expected to replace LIBs for large-scale energy storage systems. However, the development of high-energy SIBs is usually limited by the poor initial Coulombic efficiency (ICE) of the anode materials, although a series of advanced sodium storage electrode materials have been reported. This is because active sodium ions are all provided by the cathode material in a full cell. The low ICE of the anode indicates that numerous active sodium ions are irreversibly consumed during the first cycle, reducing the reversible capacity and shortening the cycle life of the full cell. The significant loss of active sodium ions is attributed to the formation of a solid electrolyte interface (SEI) on the anode side and irreversible sodium capture by defect sites and surface functional groups on the anode material. Consequently, excessive cathode material is required in the full cell, which significantly reduces the utilization rate of the cathode material and the energy density of the full cell. Furthermore, many reported cathode materials, such as Fe₂S, are sodium-deficient and cannot be directly matched with anodes, limiting the selection of electrode materials. Presodiation technology is considered the most direct and effective method to solve the state-matching problem of cathode and anode materials by compensating for active sodium-ion loss and increasing the energy density, which are crucial for the commercial application of SIBs. The aim is to eliminate the irreversible capacity loss during the first cycle by incorporating additional active sodium ions to the electrode material in advance. This review comprehensively summarizes the latest research progress on various presodiation strategies, including short circuit with sodium metal, electrochemical presodiation, sodium metal addition, chemical presodiation, and cathode sacrificial additives. The advantages and challenges of existing methods are thoroughly analyzed and discussed from the perspective of their reaction mechanism, safety, compatibility, efficiency, and scalability. Emphasis is placed on the state-of-the-art advancements in chemical presodiation and cathode sacrificial additives, which are considered the two most promising methods for commercial applications. The unresolved scientific problems and technical difficulties are further discussed from a practical perspective. This review may provide guidance for the investigation of advanced presodiation technology and promote further development of high-energy SIBs.