| Bi+N2O化学发光反应机理研究 |
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| 引用本文： | 沈关林,李学初,宁宝纲,楼南泉.Bi+N2O化学发光反应机理研究[J].物理化学学报,1988,4(1):77-79. |
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| 作者姓名： | 沈关林 李学初 宁宝纲 楼南泉 |
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| 作者单位： | Dalian Institute of Chemical Physics; Academia Sinica |
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| 摘 要： |
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| 收稿时间： | 1986-07-07 |
| 修稿时间： | 1986-11-11 |
THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N2O |
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| Shen Guanlin,Li Xuechu,Ning Baogang,Lou Nanquan.THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N2O[J].Acta Physico-Chimica Sinica,1988,4(1):77-79. |
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| Authors: | Shen Guanlin Li Xuechu Ning Baogang Lou Nanquan |
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| Institution: | Dalian Institute of Chemical Physics; Academia Sinica |
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| Abstract: | The emission spectra of BiO(A ~2Π_(1/2)) have been first obtained by studying the reaction Bi+N_2O in the heat pipe oven. 18 new bands are obtained from the emission spectra of BiO(A ~2Π_(1/2)) which are attributed to the reaction of atomic Bi~*(~2D_(3/2)) with N_2O(~1Σ_g~+). The metastable Bi~*(~2D_(3/2)) is produced by the following processes: Bi(~4S_(3/2))+N_2O(~1Σ_g~+)→BiO(X_2~2Π_(3/2)), and then,BiO(X_2~2Π_(3/2))+Bi(~4S_(3/2))→Bi~*(~2D_(3/2))+BiO(X_1~2Π_(1/2)). |
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