用于费托合成的骨架Co@HZSM-5核壳催化剂 |
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作者单位: | 1.Collaborative Innovation Center for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China;2.State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, China Petroleum & Chemical Corporation, Beijing 100083, P. R. China |
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基金项目: | The project was supported by the National Key Basic Research Program of China (973) (2012CB224804), National Natural Science Foundation of China (21373055), and Science and Technology Commission of Shanghai Municipality, China (08DZ2270500). |
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摘 要: |
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关 键 词: | 骨架Co HZSM-5 分子筛 核壳结构 费托合成 |
收稿时间: | 2015-02-02 |
Fischer-Tropsch Synthesis over Skeletal Co@HZSM-5 Core-Shell Catalysts |
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Authors: | XU Ke CHENG Yi SUN Bo PEI Yan YAN Shi-Run QIAO Ming-Hua ZHANG Xiao-Xin ZONG Bao-Ning |
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Institution: | 1.Collaborative Innovation Center for Energy Materials, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China;2.State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, China Petroleum & Chemical Corporation, Beijing 100083, P. R. China |
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Abstract: | We used skeletal Co as the core to prepare a skeletal Co@HZSM-5 core-shell catalyst by growing an HZSM-5 membrane on skeletal Co via hydrothermal synthesis. The physicochemical properties of the catalyst were determined using elemental analysis, N2 physisorption, X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and NH3 desorption. In gas-phase Fischer-Tropsch synthesis (FTS), the skeletal Co@HZSM-5 core-shell catalyst was more efficient than a physically mixed skeletal Co-HZSM-5 catalyst in cracking long-chain hydrocarbons, giving higher selectivity for C5-C11 gasoline products. The thickness of the zeolite shell on the skeletal Co@HZSM-5 core-shell catalyst was easily tuned by adjusting the hydrothermal time. At a suitable zeolite shell thickness, the long-chain hydrocarbons were cracked completely, with high FTS activity, leading to high selectivity for the gasoline fraction. Increasing the reaction temperature resulted in higher FTS and cracking activities, but the product distribution shifted to short-chain hydrocarbons. For the optimum skeletal Co@HZSM-5 core-shell catalyst, which was subjected to hydrothermal treatment for 4 d, selectivity for the gasoline fraction reached 79% at 250 ℃, which shows an excellent synergistic effect between the FTS active sites and the acidic sites on this catalyst. |
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Keywords: | Skeletal Co HZSM-5 Zeolite Core-shell structure Fischer-Tropsch synthesis |
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