| 过度金属对缺位Keggin结构杂多化合物的修复 |
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| 引用本文： | 于剑锋,秦笃捷,吴通好,王国甲,孙家鍾.过度金属对缺位Keggin结构杂多化合物的修复[J].物理化学学报,1998,14(5):435-438. |
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| 作者姓名： | 于剑锋 秦笃捷 吴通好 王国甲 孙家鍾 |
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| 作者单位： | Department of Chemistry,Institute Chemistry,Changchun 130023 |
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| 基金项目： | 国家自然科学基金!29773016 |
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| 摘 要： | 合成了第四周期过渡金属取代的Keggin结构钼磷、钨磷杂多化合物．讨论了合成条件，运用P－0键的IR振动变化表征了过渡金属离子电子组态的变化对缺位配体的修复作用．
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| 关 键 词： | 第四周期过渡金属 Keggin结构杂多化合物 缺位单取代 P-O振动 |
| 收稿时间： | 1997-08-29 |
| 修稿时间： | 1997-12-22 |
The Repair Effect of Transition-Metal Ions on the Lacunary Heteropoly Complexes with Keggin Structure |
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| Yu Jianfeng, Qing Dujie, Wu Tonghao, Wang Guojia ,Sun Chiachung.The Repair Effect of Transition-Metal Ions on the Lacunary Heteropoly Complexes with Keggin Structure[J].Acta Physico-Chimica Sinica,1998,14(5):435-438. |
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| Authors: | Yu Jianfeng Qing Dujie Wu Tonghao Wang Guojia Sun Chiachung |
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| Institution: | Department of Chemistry,Institute Chemistry,Changchun 130023 |
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| Abstract: | The 4th period transition-metal lacunary monosubstituted molybdophosphoric and tungstophosphoric complexes with Keggin structrue were synthesized. The synthesis conditions were discussed. The repair effect of the changing of the transition- metal ions electronic configu-ration on the substituted ligands was characterizated by the vibration of P-O. |
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| Keywords: | Transition-metal of the 4th period Heteropoly complexes with Keggin structure Lacunary monosubstitution Vibration of P-O |
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