| TiO2/聚丙烯酸丁酯纳米复合薄膜的制备及结构表征 |
| |
| 引用本文： | 张晟卯,张治军,党鸿辛,刘维民,薛群基.TiO2/聚丙烯酸丁酯纳米复合薄膜的制备及结构表征[J].物理化学学报,2003,19(2):171-173. |
| |
| 作者姓名： | 张晟卯 张治军 党鸿辛 刘维民 薛群基 |
| |
| 作者单位： | State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;2.Lubrication and Functional Material Laboratory, Henan University, Kaifeng 475001 |
| |
| 基金项目： | 河南省杰出人才创新基金(0121001700)资助项目~ |
| |
| 摘 要： | 利用微乳液原位聚合法在普通玻璃表面上制备了TiO2/聚丙烯酸丁酯纳米复合膜.采用傅立叶变换红外光谱、高分辨透射电子显微镜和X射线光电子能谱对膜的结构进行了表征.结果表明， TiO2以纳米线的形式弥散在聚丙烯酸丁酯的高分子网络中，并且所制备的TiO2纳米线具有板钛矿相结构.
|
| 关 键 词： | 原位聚合 二氧化钛 聚丙烯酸丁酯 纳米复合膜 |
| 收稿时间： | 2002-05-23 |
| 修稿时间： | 2002年5月23日 |
Preparation and Characterization of TiO2/Poly(butyl acrylate) Nanocomposite Film |
| |
| Zhang Sheng Mao, Zhang Zhi Jun Dang Hong Xin Liu Wei Min XueQun Ji.Preparation and Characterization of TiO2/Poly(butyl acrylate) Nanocomposite Film[J].Acta Physico-Chimica Sinica,2003,19(2):171-173. |
| |
| Authors: | Zhang Sheng Mao Zhang Zhi Jun Dang Hong Xin Liu Wei Min XueQun Ji |
| |
| Institution: | State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;2.Lubrication and Functional Material Laboratory, Henan University, Kaifeng 475001 |
| |
| Abstract: | The nano TiO2/Poly(butyl acrylate) composite film was prepared by microemulsion in situ polymerization method on glass substrate. The structure of the thin film was characterized by FTIR, XPS and HRTEM(high resolution TEM)techniques. The results of FTIR analyses indicated that the poly(butyl acrylate) networks formed through in situ polymerization. XPS results showed that Ti(OC4H9)4 changed into TiO2 through hydrolyzation. HRTEM of polymerized thin film indicated that the TiO2 nanolines are dispersed in the poly(butyl acrylate) networks. |
| |
| Keywords: | In situ polymerization Titania Poly(butyl acrylate) Nanocomposite film |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
