| 以OTS自组装单分子膜为探针研究TiO2液相空穴氧化机理 |
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| 引用本文： | 周雪锋,李伟,张妍,杨祝红,冯新,陆小华.以OTS自组装单分子膜为探针研究TiO2液相空穴氧化机理[J].物理化学学报,2007,23(7):1113-1116. |
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| 作者姓名： | 周雪锋 李伟 张妍 杨祝红 冯新 陆小华 |
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| 作者单位： | Department of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China |
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| 基金项目： | 国家自然科学基金;国家杰出青年科学基金海外合作基金;国家重点基础研究发展计划(973计划);江苏省自然科学基金;江苏省自然科学基金 |
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| 摘 要： | 通过引入十八烷基三氯硅烷(OTS)自组装单分子膜作为氧化反应的探针, 在排除反应物的吸附和扩散的条件下研究溶胶-凝胶制备的TiO2薄膜表面光催化空穴氧化初始过程. 研究结果表明, 在紫外光照下, 水溶液中OTS部分覆盖的TiO2表面能够很快从憎水变成亲水. 存在空穴捕获剂后, TiO2表面OTS自组装单分子膜碳链的脱除受到明显抑制, 水接触角随光照时间变化非常小; 而水中羟基自由基捕获剂或者F-的存在则对TiO2表面OTS自组装单分子膜碳链的脱除几乎无影响. 这表明, 空穴氧化在TiO2表面OTS自组装单分子膜碳链的脱除中占主要地位.
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| 关 键 词： | 光催化 机理 空穴氧化 牺牲剂 自组装单分子膜 |
| 收稿时间： | 2006-12-13 |
| 修稿时间： | 2006-12-132007-01-31 |
Hole Oxidation on TiO2 Films in Aqueous Solutions Studied by Using OTS SAMs as a Probe |
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| ZHOU Xue-Feng,LI Wei,ZHANG Yan,YANG Zhu-Hong,FENG Xin,LU Xiao-Hua.Hole Oxidation on TiO2 Films in Aqueous Solutions Studied by Using OTS SAMs as a Probe[J].Acta Physico-Chimica Sinica,2007,23(7):1113-1116. |
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| Authors: | ZHOU Xue-Feng LI Wei ZHANG Yan YANG Zhu-Hong FENG Xin LU Xiao-Hua |
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| Institution: | Department of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, P. R. China |
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| Abstract: | An approach was developed to investigate hole oxidation on TiO2 films in aqueous solutions by using octadecyltrichlorosilane (OTS) self-assembled monolayers (SAMs) as a probe, in which the adsorption and surface diffusion of the reactants were exculded. Under UV irradiation, the water contact angle of the OTS SAMs on TiO2films in water decreased obviously. In the presence of hole scavengers, the decrease of water contact angle for the OTS fluoride on the decrease of water contact angle was very small. It indicated that direct hole oxidation played a major role in photocatalytic removal of alkyl chains on TiO2 films in aqueous solutions. |
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| Keywords: | Photocatalysis Mechanism Hole oxidation Scavenger SAMs |
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