| 多孔聚乙酰苯胺纳米纤维载铂催化剂对甲醇的电催化氧化 |
| |
| 引用本文： | 赵彦春,兰黄鲜,田建袅,杨秀林,王凤阳.多孔聚乙酰苯胺纳米纤维载铂催化剂对甲醇的电催化氧化[J].物理化学学报,2009,25(10):2050-2054. |
| |
| 作者姓名： | 赵彦春 兰黄鲜 田建袅 杨秀林 王凤阳 |
| |
| 作者单位： | Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources of the Ministry of Education of China, College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, Guangxi Province, P. R. China |
| |
| 基金项目： | China，Science and Research Foundation of Guangxi Ministry of Education，Young Key Teacher Foundation of Guangxi Normal University and Innovation Project of Guangxi Graduate Education;China (2008M021).广西青年科学基金，广西教育厅科研项目，广西师范大学青年骨干教师基金和广西师范大学研究生教育创新计划 |
| |
| 摘 要： | 采用简单的化学氧化聚合法制备了新型多孔结构的聚乙酰苯胺纳米纤维(np-PAANI), 并以此为载体在络合剂的存在下合成了Pt纳米微粒修饰的np-PAANI复合物膜电极C/np-PAANI/Pt. 样品的形貌和结构通过扫描电镜(SEM)、透射电镜(TEM)和X射线衍射(XRD)进行了表征. 在0.5 mol·L-1 CH3OH+0.5 mol·L-1 H2SO4混合溶液中考察了C/np-PAANI/Pt催化剂对甲醇的电催化氧化性能. 结果表明, 以np-PAANI负载的Pt催化剂对甲醇的电催化氧化活性和稳定性都比普通PAANI结构及石墨粉负载的Pt催化剂好很多.
|
| 关 键 词： | 聚N-乙酰苯胺 铂微粒 多孔结构 甲醇 电催化氧化 |
| 收稿时间： | 2009-04-12 |
| 修稿时间： | 2009-08-26 |
Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils |
| |
| ZHAO Yan-Chun,LAN Huang-Xian,TIAN Jian-Niao,YANG Xiu-Lin,WANG Feng-Yang.Electrocatalytic Oxidation of Methanol on Pt Nanoparticles Supported on Porous Poly(N-acetylaniline) Nanofibrils[J].Acta Physico-Chimica Sinica,2009,25(10):2050-2054. |
| |
| Authors: | ZHAO Yan-Chun LAN Huang-Xian TIAN Jian-Niao YANG Xiu-Lin WANG Feng-Yang |
| |
| Institution: | Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources of the Ministry of Education of China, College of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, Guangxi Province, P. R. China |
| |
| Abstract: | A novel nanoporous poly(N-acetylaniline) (np-PAANI) film with a network structure modified with Pt nanoparticles (C/np-PAANI/Pt) was fabricated using chemical oxidation polymerization and a reduction method. The morphology and composition of the final products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The electrocatalytic activity of C/np-PAANI/Pt towards the oxidation of methanol was investigated using cyclic voltammetry and chronoamperometric methods in 0.5 mol·L-1 CH3OH+0.5 mol·L-1 H2SO4 mixture solution. Results indicated that C/np-PAANI/Pt catalysts exhibited improved electrocatalytic activity, anti-poisoning ability, and good stability towards methanol oxidation by comparison to C/PAANI/Pt or C/Pt. |
| |
| Keywords: | Poly(N-acetylaniline) Pt particles Nanoporous structure Methanol Electrocatalytic oxidation |
| 本文献已被 万方数据 等数据库收录！ |
| 点击此处可从《物理化学学报》浏览原始摘要信息 |
| 点击此处可从《物理化学学报》下载免费的PDF全文 |
