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储氢合金电极中添加碳纳米管对SC型高功率电池性能的影响
引用本文:陈雨婷,张海燕,张国庆,陈易明,朱清峰.储氢合金电极中添加碳纳米管对SC型高功率电池性能的影响[J].物理化学学报,2008,24(3):527-532.
作者姓名:陈雨婷  张海燕  张国庆  陈易明  朱清峰
作者单位:Faculty of Material and Energy, Guangdong University of Technology, Guanzhou 510006, P. R. China
基金项目:国家自然科学基金(50372013)、高等学校博士学科点专项科研基金(20050562002)、广东省自然科学基金(07001769)、广东省教育厅自然科学研究项目(04Z005)资助
摘    要:在SC型高功率镍氢电池的负极中添加不同含量的碳纳米管制备SC型高功率镍氢电池, 并对其容量、大电流放电性能和循环寿命进行研究. 结果发现, 碳纳米管的加入有利于提高电池的综合性能, 尤其是大电流放电性能和循环寿命; 加入碳纳米管的含量为0.8%(w)时电池的综合性能最好, 其最高容量达到3369 mAh, 2C(6000 mA)循环600次后容量仍然保持在3280 mAh(97% DOD(放电深度))以上, 5C(15000 mA)循环180 次容量仍然有2850 mAh(89.1% DOD)以上.

关 键 词:SC型高功率镍氢电池  碳纳米管  容量  循环寿命  大电流放电性能  
收稿时间:2007-08-15
修稿时间:2007年8月15日

Influence of Addition of Carbon Nanotubes in the Hydrogen Storage Alloy Electrode on the Performance of SC High Power Batteries
CHEN Yu-Ting,ZHANG Hai-Yan,ZHANG Guo-Qing,CHEN Yi-Ming,ZHU Qing-Feng.Influence of Addition of Carbon Nanotubes in the Hydrogen Storage Alloy Electrode on the Performance of SC High Power Batteries[J].Acta Physico-Chimica Sinica,2008,24(3):527-532.
Authors:CHEN Yu-Ting  ZHANG Hai-Yan  ZHANG Guo-Qing  CHEN Yi-Ming  ZHU Qing-Feng
Institution:Faculty of Material and Energy, Guangdong University of Technology, Guanzhou 510006, P. R. China
Abstract:The carbon nanotubes were added to the cathode to prepare SC high-power Ni/MH batteries. The capacity, large-current discharging performance and cycle life were investigated. It was found that adding carbon nanotubes was greatly advantageous to enhance the batteries’ overall performance, especially the large-rate discharge performance and cycle life. When the weight ratio of the MWNTs in the compound electrode was 0.8%(w), the overall performance of the battery was the best, which showed a highest capacity of 3369 mAh in the condition of 3000 mA charge current and 6000 mA discharge current (2C-rate discharge), and the cycle life surpassed 600 times, the capacities passed 3280 mAh (97% DOD (depth of discharge)). Especially in the condition of 5C-rate large-current discharge (3000 mAh charge current and 15000 mA discharge current), its cycle life surpassed 180 times (89.1% DOD).
Keywords:SC high-power Ni/MH batteries  CNTs  Capacity  Cycle life  Large-current discharging performance
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