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染料敏化TiO2/MoO3薄膜电池的光电变色
引用本文:张莉,任焱杰,蔡生民.染料敏化TiO2/MoO3薄膜电池的光电变色[J].物理化学学报,2001,17(9):817-819.
作者姓名:张莉  任焱杰  蔡生民
作者单位:College of Chemistry and Molecular Engineering, Peking University,Beijing 100871;Suzhou Teacher′s College of Anhui Province, Suzhou 234000
基金项目:国家自然科学基金(20073003)、安徽省教委自然科学基金(99j10211)和中国科学院有机固体开放实验室部分资助项目
摘    要:在导电玻璃上电沉积得到MoO3薄膜,该薄膜具有良好的电致变色特性,用它和顺二硫氰根 双(2,2′ 联吡啶 4,4′ 二羧酸)合钌(II)cis bis(thiocyanato) bis(2,2′ bipyridyl 4,4′ dicarboxylate)ruthenium(II),简写为RuL2(SCN)2]染料敏化的TiO2纳米结构多孔膜组成电池,在白光照射下可产生显著的颜色变化,有望用于自供电源的电色灵巧窗(self powered smart window).

关 键 词:光电变色  MoO3薄膜  电沉积  自供电源灵巧窗  
收稿时间:2001-03-14
修稿时间:2001年3月14日

Photoelectrochromism of Dye-sensitized Nanoporous TiO2 Film Combined with Electrodeposited MoO3 Film
Zhang Li,Ren Yan- Jie Cai Sheng- Min.Photoelectrochromism of Dye-sensitized Nanoporous TiO2 Film Combined with Electrodeposited MoO3 Film[J].Acta Physico-Chimica Sinica,2001,17(9):817-819.
Authors:Zhang Li  Ren Yan- Jie Cai Sheng- Min
Institution:College of Chemistry and Molecular Engineering, Peking University,Beijing 100871;Suzhou Teacher′s College of Anhui Province, Suzhou 234000
Abstract:A self- powered smart window was achieved by combining a dye- sensitized nanoporous TiO2 film as photovoltaic layer with an electrodeposited MoO3 film as electrochromic layer. This window changed from almost transparent to blue spontaneously under illumination, and thus could modulate light transmittance.
Keywords:Photoelectrochromism  Molybdenun oxide  Electrodeposition  Self- powered smart window
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