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有序自组装聚合物纳米结构
引用本文:于春玲,翟锦,葛红莉,万梅香,江雷,李泽生,李铁津.有序自组装聚合物纳米结构[J].物理化学学报,2004,20(10):1258-1261.
作者姓名:于春玲  翟锦  葛红莉  万梅香  江雷  李泽生  李铁津
作者单位:Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080; College of Chemistry, Jilin University, Changchun  130023
基金项目:国家重点基础研究发展规划项目(G1999064504),国家自然科学基金(20125102,20341003)资助项目~~
摘    要:采用水辅助方法(water-assisted fabrication method),分别以4-十二烷基苯磺酸掺杂的聚苯胺(PANI-DBSA)和聚2-甲氧基-5-(2′-乙烯基-己氧基)苯乙炔(MEH-PPV)两种功能高聚物为成膜材料,冷凝水滴为模板,利用水滴在聚合物溶液表面的自组装,制备出了两种纳米层次以上的蜂窝状有序多孔聚合物薄膜.通过原子力显微镜和共聚焦荧光显微镜对其形貌、电学性质和荧光图像进行了表征.

关 键 词:水辅助方法  蜂窝状结构  有序多孔薄膜  PANI-DBSA  MEH-PPV  
收稿时间:2004-05-12
修稿时间:2004年5月12日

Ordered Self-assembly of Polymer Nano-structure
Yu Chun Ling, Zhai Jin Ge Hong Li Wan Mei Xiang Jiang Lei Li Ze ShengLi Tie Jin.Ordered Self-assembly of Polymer Nano-structure[J].Acta Physico-Chimica Sinica,2004,20(10):1258-1261.
Authors:Yu Chun Ling  Zhai Jin Ge Hong Li Wan Mei Xiang Jiang Lei Li Ze ShengLi Tie Jin
Institution:Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080; College of Chemistry, Jilin University, Changchun  130023
Abstract:The functional polymers of 4-dodecylbenzenesulfonic acid-doped polyaniline (PANI-DBSA) and poly(2-methoxy-5-(2’-ethyl-hexloxy)-p-phenylene-vinylene) (MEH-PPV) are adopted as film formation materials, and two kinds of ordered honeycomb nano/micro structures are successfully fabricated by water assisted self-assembly method using water droplet as template. The film morphology, electric and luminescent properties are studied in detail by atomic force microscopy and confocal fluorescent microscopy.
Keywords:Water  assisted fabrication method      Honeycomb structure  Ordered porous film                      PANI  DBSA  MEH  PPV
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