MoS_2/TiO_2复合催化剂的制备及其在紫外光下的光催化制氢活性 |
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作者单位: | 1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;2. CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China |
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基金项目: | the Ministry of Science and Technology of China(2016YFA0200900);the Ministry of Science and Technology of China(2016YFF0203803) |
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摘 要: | 为了研究复合光催化剂在光催化中的制氢效率,采用水热法制备了Mo S2纳米片,然后通过水热法在Mo S2纳米片上负载了TiO_2纳米颗粒,形成了Mo S2/TiO_2异质结复合催化剂。采用冷场发射扫描电子显微镜(FE-SEM)、透射电子显微镜(TEM)、X射线衍射(XRD)、紫外-可见吸收光谱(UV-Vis)、拉曼光谱(Raman),X射线光电子能谱(XPS)对材料的结构和光学性能表征并进行分析。通过光催化制氢测试对光催化剂进行评价,实验结果表明,在波长为365 nm的紫外光照射下,最高光催化制氢速率为1004μmol·h-1·g-1,对应的催化剂的Mo S2含量为30%,其催化速率远大于单一的Mo S2和TiO_2,表明Mo S2/TiO_2复合催化剂在紫外光照下能显著提高光催化产氢性能。基于Mo S2/TiO_2复合光催化剂优越的光催化产氢性能,本文对复合光催化剂的产氢机理做了研究和分析。
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关 键 词: | 二氧化钛 二硫化钼 异质结 复合结构 光催化制氢 |
收稿时间: | 2017-01-16 |
Preparation of MoS2/TiO2 Composite Catalyst and Its Photocatalytic Hydrogen Production Activity under UV Irradiation |
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Authors: | Chi ZHANG Zhi-Jiao WU Jian-Jun LIU Ling-Yu PIAO |
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Institution: | 1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China;2. CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, P. R. China |
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Abstract: | To study the activity of a composite photocatalyst for photocatalytic hydrogen production, we prepared and loaded MoS2 nanosheets with TiO2 nanoparticles using a hydrothermal method, thus forming a MoS2/TiO2 heterojunction composite catalyst. The structural and optical properties of the catalyst were characterized and analyzed by field-emission scanning electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, UV-Vis absorption spectra, Raman spectroscopy, and X-ray photoelectron spectroscopy. The activity of the photocatalyst was evaluated by its photocatalytic hydrogen production rate. The corresponding MoS2 content of the catalyst was found to be 30%, and upon the exposure to 365nm UV light, a high photocatalytic hydrogen production rate of 1004 μmol-1·h-1·g-1 was obtained. The catalytic rate is much greater than that obtained with MoS2 or TiO2 catalysts. The high hydrogen production rate indicated that the use of a MoS2/TiO2 composite catalyst can significantly improve the UV-induced photocatalytic hydrogen production performance. Because of the excellent photocatalytic hydrogen production performance of the MoS2/TiO2 composite, we studied and analyzed the hydrogen production mechanism. |
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Keywords: | TiO2 MoS2 Composite structure Heterojunction Photocatalytic hydrogen production |
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