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苯热条件下GaP纳米晶的稳定性
引用本文:信春雨,高善民,崔得良,黄柏标,秦晓燕,蒋民华.苯热条件下GaP纳米晶的稳定性[J].物理化学学报,1999,15(2):105-109.
作者姓名:信春雨  高善民  崔得良  黄柏标  秦晓燕  蒋民华
作者单位:Library of Shandong University;Institute of Crystal Materials,Shandong University,Jinan 250100
摘    要:用高温高压苯热合成方法制备了GaP纳米晶,用X射线衍射、光吸收谱及透射电子显微镜对所得样品进行了分析测试.结果表明,GaP纳米晶在苯热条件下是亚稳定态的,反应时间过长及反应温度过高均不利于它的生成和生长.文中还讨论了晶粒度分布与合成条件间的关系,并进行了理论上的定性分析.

关 键 词:GaP纳米晶  苯热合成  光吸收  
收稿时间:1998-04-02
修稿时间:1998-06-12

The Stability of GaP Nanocrystals under Benzene Thermal Conditions
Xin Chunyu, Gao Shanmin, Cui Deliang ,Huaug Baibiao, Qin Xiaoyan ,Jiang Minhua.The Stability of GaP Nanocrystals under Benzene Thermal Conditions[J].Acta Physico-Chimica Sinica,1999,15(2):105-109.
Authors:Xin Chunyu  Gao Shanmin  Cui Deliang  Huaug Baibiao  Qin Xiaoyan  Jiang Minhua
Institution:Library of Shandong University;Institute of Crystal Materials,Shandong University,Jinan 250100
Abstract:GaP nanocrystals were synthesized by high temperature high pressure beuzene ther-inal synthesis method, the samples were charartrized by X-ray cliffraction,optical absorption and transmission election microscope. The results showed that GaP nanocrystals were metastable un-der benzene thermaJ conditions. The relationship between the size distriblltion and the synthesis conditiolis was also investigated iu this paper.
Keywords:GaP nanocrystals  Benzcne thermal synthesis  Optical absorption
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